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Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate
In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°....
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915380/ https://www.ncbi.nlm.nih.gov/pubmed/21200900 http://dx.doi.org/10.1107/S1600536807067037 |
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author | Singh, Mamata Srivastava, Ajay K. Singh, N. K. Shrivastav, Anuraag Sharma, R. K. |
author_facet | Singh, Mamata Srivastava, Ajay K. Singh, N. K. Shrivastav, Anuraag Sharma, R. K. |
author_sort | Singh, Mamata |
collection | PubMed |
description | In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The molecular conformation is stabilized by intramolecular O—H⋯O and N—H⋯S hydrogen bonds, while intermolecular N—H⋯O, N—H⋯N and weak C—H⋯O interactions help to stabilize the crystal structure. |
format | Text |
id | pubmed-2915380 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29153802010-12-30 Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate Singh, Mamata Srivastava, Ajay K. Singh, N. K. Shrivastav, Anuraag Sharma, R. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The molecular conformation is stabilized by intramolecular O—H⋯O and N—H⋯S hydrogen bonds, while intermolecular N—H⋯O, N—H⋯N and weak C—H⋯O interactions help to stabilize the crystal structure. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915380/ /pubmed/21200900 http://dx.doi.org/10.1107/S1600536807067037 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Singh, Mamata Srivastava, Ajay K. Singh, N. K. Shrivastav, Anuraag Sharma, R. K. Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title | Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_full | Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_fullStr | Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_full_unstemmed | Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_short | Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_sort | triethylammonium n′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915380/ https://www.ncbi.nlm.nih.gov/pubmed/21200900 http://dx.doi.org/10.1107/S1600536807067037 |
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