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Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate

In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°....

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Autores principales: Singh, Mamata, Srivastava, Ajay K., Singh, N. K., Shrivastav, Anuraag, Sharma, R. K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915380/
https://www.ncbi.nlm.nih.gov/pubmed/21200900
http://dx.doi.org/10.1107/S1600536807067037
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author Singh, Mamata
Srivastava, Ajay K.
Singh, N. K.
Shrivastav, Anuraag
Sharma, R. K.
author_facet Singh, Mamata
Srivastava, Ajay K.
Singh, N. K.
Shrivastav, Anuraag
Sharma, R. K.
author_sort Singh, Mamata
collection PubMed
description In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O and N—H⋯S hydrogen bonds, while inter­molecular N—H⋯O, N—H⋯N and weak C—H⋯O inter­actions help to stabilize the crystal structure.
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spelling pubmed-29153802010-12-30 Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate Singh, Mamata Srivastava, Ajay K. Singh, N. K. Shrivastav, Anuraag Sharma, R. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(16)N(+)·C(15)H(13)N(2)O(2)S(2) (−), the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O and N—H⋯S hydrogen bonds, while inter­molecular N—H⋯O, N—H⋯N and weak C—H⋯O inter­actions help to stabilize the crystal structure. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915380/ /pubmed/21200900 http://dx.doi.org/10.1107/S1600536807067037 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Singh, Mamata
Srivastava, Ajay K.
Singh, N. K.
Shrivastav, Anuraag
Sharma, R. K.
Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate
title Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate
title_full Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate
title_fullStr Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate
title_full_unstemmed Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate
title_short Triethyl­ammonium N′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate
title_sort triethyl­ammonium n′-(benzyl­sulfanylthio­carbonyl)-2-hydroxy­benzohydrazidate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915380/
https://www.ncbi.nlm.nih.gov/pubmed/21200900
http://dx.doi.org/10.1107/S1600536807067037
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