N-(3,4-Dimethyl­phen­yl)benzamide

The conformation of the NH bond in the structure of the title compound (N34DMPBA), C(15)H(15)NO, is anti to the meta-methyl substituent in the aniline ring, similar to that observed with respect to the meta-chloro substituent in N-(3,4-dichloro­phen­yl)benzamide (N34DCPBA), but in contrast to the sy...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef, Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915381/
https://www.ncbi.nlm.nih.gov/pubmed/21200902
http://dx.doi.org/10.1107/S1600536807066937
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author Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The conformation of the NH bond in the structure of the title compound (N34DMPBA), C(15)H(15)NO, is anti to the meta-methyl substituent in the aniline ring, similar to that observed with respect to the meta-chloro substituent in N-(3,4-dichloro­phen­yl)benzamide (N34DCPBA), but in contrast to the syn conformation observed with respect to the meta-methyl substituent in N-(3,4-dimethyl­phen­yl)acetamide. The bond parameters in N34DMPBA are similar to those in N34DCPBA and other benzanilides. The mol­ecules in N34DMPBA are packed into a column-like structure in the direction of the a axis through N—H⋯O hydrogen bonds.
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spelling pubmed-29153812010-12-30 N-(3,4-Dimethyl­phen­yl)benzamide Gowda, B. Thimme Tokarčík, Miroslav Kožíšek, Jozef Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformation of the NH bond in the structure of the title compound (N34DMPBA), C(15)H(15)NO, is anti to the meta-methyl substituent in the aniline ring, similar to that observed with respect to the meta-chloro substituent in N-(3,4-dichloro­phen­yl)benzamide (N34DCPBA), but in contrast to the syn conformation observed with respect to the meta-methyl substituent in N-(3,4-dimethyl­phen­yl)acetamide. The bond parameters in N34DMPBA are similar to those in N34DCPBA and other benzanilides. The mol­ecules in N34DMPBA are packed into a column-like structure in the direction of the a axis through N—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2915381/ /pubmed/21200902 http://dx.doi.org/10.1107/S1600536807066937 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Sowmya, B. P.
Fuess, Hartmut
N-(3,4-Dimethyl­phen­yl)benzamide
title N-(3,4-Dimethyl­phen­yl)benzamide
title_full N-(3,4-Dimethyl­phen­yl)benzamide
title_fullStr N-(3,4-Dimethyl­phen­yl)benzamide
title_full_unstemmed N-(3,4-Dimethyl­phen­yl)benzamide
title_short N-(3,4-Dimethyl­phen­yl)benzamide
title_sort n-(3,4-dimethyl­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915381/
https://www.ncbi.nlm.nih.gov/pubmed/21200902
http://dx.doi.org/10.1107/S1600536807066937
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AT tokarcikmiroslav n34dimethylphenylbenzamide
AT kozisekjozef n34dimethylphenylbenzamide
AT sowmyabp n34dimethylphenylbenzamide
AT fuesshartmut n34dimethylphenylbenzamide

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