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A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres
The catalytic enantioselective synthesis of densely functionalised organic molecules containing all-carbon quaternary stereocentres is a challenge to modern chemical methodology research. The catalytically controlled asymmetric α-alkylation of ketones represents another difficult task and has been o...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2917108/ https://www.ncbi.nlm.nih.gov/pubmed/20697457 http://dx.doi.org/10.1038/nchem.518 |