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Recent advances in carbocupration of α-heterosubstituted alkynes
Carbocupration of α-heterosubstituted alkynes leads to the formation of stereodefined functionalized vinyl copper species as single isomer. Recent advances in the field show that a simple pre-association of the organometallic derivative with an additional polar functional group in the vicinity of th...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
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Beilstein-Institut
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919272/ https://www.ncbi.nlm.nih.gov/pubmed/20703385 http://dx.doi.org/10.3762/bjoc.6.77 |
| _version_ | 1782185167841918976 |
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| author | Basheer, Ahmad Marek, Ilan |
| author_facet | Basheer, Ahmad Marek, Ilan |
| author_sort | Basheer, Ahmad |
| collection | PubMed |
| description | Carbocupration of α-heterosubstituted alkynes leads to the formation of stereodefined functionalized vinyl copper species as single isomer. Recent advances in the field show that a simple pre-association of the organometallic derivative with an additional polar functional group in the vicinity of the reaction center may completely change the stereochemical outcome of the reaction. Representative examples are given in this mini-review. |
| format | Text |
| id | pubmed-2919272 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29192722010-08-11 Recent advances in carbocupration of α-heterosubstituted alkynes Basheer, Ahmad Marek, Ilan Beilstein J Org Chem Review Carbocupration of α-heterosubstituted alkynes leads to the formation of stereodefined functionalized vinyl copper species as single isomer. Recent advances in the field show that a simple pre-association of the organometallic derivative with an additional polar functional group in the vicinity of the reaction center may completely change the stereochemical outcome of the reaction. Representative examples are given in this mini-review. Beilstein-Institut 2010-07-15 /pmc/articles/PMC2919272/ /pubmed/20703385 http://dx.doi.org/10.3762/bjoc.6.77 Text en Copyright © 2010, Basheer and Marek https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Review Basheer, Ahmad Marek, Ilan Recent advances in carbocupration of α-heterosubstituted alkynes |
| title | Recent advances in carbocupration of α-heterosubstituted alkynes |
| title_full | Recent advances in carbocupration of α-heterosubstituted alkynes |
| title_fullStr | Recent advances in carbocupration of α-heterosubstituted alkynes |
| title_full_unstemmed | Recent advances in carbocupration of α-heterosubstituted alkynes |
| title_short | Recent advances in carbocupration of α-heterosubstituted alkynes |
| title_sort | recent advances in carbocupration of α-heterosubstituted alkynes |
| topic | Review |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919272/ https://www.ncbi.nlm.nih.gov/pubmed/20703385 http://dx.doi.org/10.3762/bjoc.6.77 |
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