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catena-Poly[[diaquamanganese(II)]-μ-pyridine-2,4,6-tricarboxylato-κ(5) N,O (2),O (6):O (4),O (4′)]
In the title compound, [Mn(C(8)H(2)NO(6))(H(2)O)(2)](n), each pyridine-2,4,6-tricarboxylate (tpc) ligand bridges two Mn(II) ions with the formation of polymeric chains located on a twofold rotation axis. Each Mn(II) ion is coordinated by two O and one N atoms from one tpc ligand, two O atoms from a...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919291/ https://www.ncbi.nlm.nih.gov/pubmed/21200609 http://dx.doi.org/10.1107/S1600536807058102 |
Sumario: | In the title compound, [Mn(C(8)H(2)NO(6))(H(2)O)(2)](n), each pyridine-2,4,6-tricarboxylate (tpc) ligand bridges two Mn(II) ions with the formation of polymeric chains located on a twofold rotation axis. Each Mn(II) ion is coordinated by two O and one N atoms from one tpc ligand, two O atoms from another ligand and two water molecules in a distorted pentagonal–bipyramidal geometry. The Mn—N [2.243 (2) Å] and Mn—O [2.206 (2)–2.3123 (16) Å] bond lengths are normal. The coordinated water molecules link neighbouring polymeric chains via O—H⋯O hydrogen bonds into a two-dimensional framework parallel to the bc plane. |
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