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catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]

In the title compound, [Mn(C(8)H(2)NO(6))(H(2)O)(2)](n), each pyridine-2,4,6-tricarboxyl­ate (tpc) ligand bridges two Mn(II) ions with the formation of polymeric chains located on a twofold rotation axis. Each Mn(II) ion is coordinated by two O and one N atoms from one tpc ligand, two O atoms from a...

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Detalles Bibliográficos
Autores principales: Fu, Da-Wei, Xu, Hai-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919291/
https://www.ncbi.nlm.nih.gov/pubmed/21200609
http://dx.doi.org/10.1107/S1600536807058102
Descripción
Sumario:In the title compound, [Mn(C(8)H(2)NO(6))(H(2)O)(2)](n), each pyridine-2,4,6-tricarboxyl­ate (tpc) ligand bridges two Mn(II) ions with the formation of polymeric chains located on a twofold rotation axis. Each Mn(II) ion is coordinated by two O and one N atoms from one tpc ligand, two O atoms from another ligand and two water mol­ecules in a distorted penta­gonal–bipyramidal geometry. The Mn—N [2.243 (2) Å] and Mn—O [2.206 (2)–2.3123 (16) Å] bond lengths are normal. The coordinated water mol­ecules link neighbouring polymeric chains via O—H⋯O hydrogen bonds into a two-dimensional framework parallel to the bc plane.