catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]

In the title compound, [Mn(C(8)H(2)NO(6))(H(2)O)(2)](n), each pyridine-2,4,6-tricarboxyl­ate (tpc) ligand bridges two Mn(II) ions with the formation of polymeric chains located on a twofold rotation axis. Each Mn(II) ion is coordinated by two O and one N atoms from one tpc ligand, two O atoms from a...

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Detalles Bibliográficos
Autores principales: Fu, Da-Wei, Xu, Hai-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919291/
https://www.ncbi.nlm.nih.gov/pubmed/21200609
http://dx.doi.org/10.1107/S1600536807058102
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author Fu, Da-Wei
Xu, Hai-Jun
author_facet Fu, Da-Wei
Xu, Hai-Jun
author_sort Fu, Da-Wei
collection PubMed
description In the title compound, [Mn(C(8)H(2)NO(6))(H(2)O)(2)](n), each pyridine-2,4,6-tricarboxyl­ate (tpc) ligand bridges two Mn(II) ions with the formation of polymeric chains located on a twofold rotation axis. Each Mn(II) ion is coordinated by two O and one N atoms from one tpc ligand, two O atoms from another ligand and two water mol­ecules in a distorted penta­gonal–bipyramidal geometry. The Mn—N [2.243 (2) Å] and Mn—O [2.206 (2)–2.3123 (16) Å] bond lengths are normal. The coordinated water mol­ecules link neighbouring polymeric chains via O—H⋯O hydrogen bonds into a two-dimensional framework parallel to the bc plane.
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spelling pubmed-29192912010-12-30 catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)] Fu, Da-Wei Xu, Hai-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(8)H(2)NO(6))(H(2)O)(2)](n), each pyridine-2,4,6-tricarboxyl­ate (tpc) ligand bridges two Mn(II) ions with the formation of polymeric chains located on a twofold rotation axis. Each Mn(II) ion is coordinated by two O and one N atoms from one tpc ligand, two O atoms from another ligand and two water mol­ecules in a distorted penta­gonal–bipyramidal geometry. The Mn—N [2.243 (2) Å] and Mn—O [2.206 (2)–2.3123 (16) Å] bond lengths are normal. The coordinated water mol­ecules link neighbouring polymeric chains via O—H⋯O hydrogen bonds into a two-dimensional framework parallel to the bc plane. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2919291/ /pubmed/21200609 http://dx.doi.org/10.1107/S1600536807058102 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Fu, Da-Wei
Xu, Hai-Jun
catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]
title catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]
title_full catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]
title_fullStr catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]
title_full_unstemmed catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]
title_short catena-Poly[[diaqua­manganese(II)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) N,O (2),O (6):O (4),O (4′)]
title_sort catena-poly[[diaqua­manganese(ii)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(5) n,o (2),o (6):o (4),o (4′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919291/
https://www.ncbi.nlm.nih.gov/pubmed/21200609
http://dx.doi.org/10.1107/S1600536807058102
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