catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato]

The title compound, [Sn(C(4)H(9))(3)(C(6)H(5)O(2)S)](n), possesses an infinite chain structure. The SnO(2)C(3) centre has a distorted trigonal-bipyramidal geometry (τ = 0.145) with the O atoms in the axial positions. Atoms of the thio­phene group S1 and C4 are disordered over two sites The S atom an...

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Detalles Bibliográficos
Autores principales: Wang, Hongyun, Yin, Handong, Sun, Yuying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919292/
https://www.ncbi.nlm.nih.gov/pubmed/21200650
http://dx.doi.org/10.1107/S1600536807063623
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author Wang, Hongyun
Yin, Handong
Sun, Yuying
author_facet Wang, Hongyun
Yin, Handong
Sun, Yuying
author_sort Wang, Hongyun
collection PubMed
description The title compound, [Sn(C(4)H(9))(3)(C(6)H(5)O(2)S)](n), possesses an infinite chain structure. The SnO(2)C(3) centre has a distorted trigonal-bipyramidal geometry (τ = 0.145) with the O atoms in the axial positions. Atoms of the thio­phene group S1 and C4 are disordered over two sites The S atom and one C atom, with attached H atom, of the thiophene ring are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.
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spelling pubmed-29192922010-12-30 catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato] Wang, Hongyun Yin, Handong Sun, Yuying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(4)H(9))(3)(C(6)H(5)O(2)S)](n), possesses an infinite chain structure. The SnO(2)C(3) centre has a distorted trigonal-bipyramidal geometry (τ = 0.145) with the O atoms in the axial positions. Atoms of the thio­phene group S1 and C4 are disordered over two sites The S atom and one C atom, with attached H atom, of the thiophene ring are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2919292/ /pubmed/21200650 http://dx.doi.org/10.1107/S1600536807063623 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wang, Hongyun
Yin, Handong
Sun, Yuying
catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato]
title catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato]
title_full catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato]
title_fullStr catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato]
title_full_unstemmed catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato]
title_short catena-Poly[[tri-n-butyl­tin(IV)]-μ-2-thio­phene­acetato]
title_sort catena-poly[[tri-n-butyl­tin(iv)]-μ-2-thio­phene­acetato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2919292/
https://www.ncbi.nlm.nih.gov/pubmed/21200650
http://dx.doi.org/10.1107/S1600536807063623
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AT sunyuying catenapolytrinbutyltinivm2thiopheneacetato

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