{4,4′-Dimeth­oxy-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenolato}copper(II)

The title complex, [Cu(C(18)H(18)N(2)O(6))], was synthesized by the reaction of copper(II) acetate mono­hydrate with the ligand 4,4′-dimeth­oxy-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenol (H(2) L). The Cu atom is coordinated by two O atoms and two N atoms of the L (2−) unit. A bridged di...

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Detalles Bibliográficos
Autores principales: Sun, Yin-Xia, Gao, Su-Xia, Shi, Jun-Yan, Dong, Wen-Kui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2924182/
https://www.ncbi.nlm.nih.gov/pubmed/21200572
http://dx.doi.org/10.1107/S1600536807061752
Descripción
Sumario:The title complex, [Cu(C(18)H(18)N(2)O(6))], was synthesized by the reaction of copper(II) acetate mono­hydrate with the ligand 4,4′-dimeth­oxy-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenol (H(2) L). The Cu atom is coordinated by two O atoms and two N atoms of the L (2−) unit. A bridged dimer is formed through inter­molecular Cu⋯O inter­actions [Cu⋯O = 1.9408 (15) Å], creating a distorted square-pyramidal geometry about the Cu atoms.

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