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Substitutional disorder in a hypervalent diorganotin(IV) dihalide
The structure of bromidochloridobis[2-(dimethylaminomethyl)phenyl]tin(IV), [SnBr(0.65)Cl(1.35)(C(9)H(12)N)(2)], contains two 2-(Me(2)NCH(2))C(6)H(4) units bonded to a Sn atom which lies on a twofold axis. The compound exhibits substitutional disorder of the halide atoms bonded to the Sn, with 1....
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2947775/ https://www.ncbi.nlm.nih.gov/pubmed/21200616 http://dx.doi.org/10.1107/S1600536807063386 |
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author | Rotar, Adina Varga, Richard A. Silvestru, Cristian |
author_facet | Rotar, Adina Varga, Richard A. Silvestru, Cristian |
author_sort | Rotar, Adina |
collection | PubMed |
description | The structure of bromidochloridobis[2-(dimethylaminomethyl)phenyl]tin(IV), [SnBr(0.65)Cl(1.35)(C(9)H(12)N)(2)], contains two 2-(Me(2)NCH(2))C(6)H(4) units bonded to a Sn atom which lies on a twofold axis. The compound exhibits substitutional disorder of the halide atoms bonded to the Sn, with 1.35 occupancy for Cl and 0.65 for Br; it is isomorphous with the corresponding dichloride. The Sn atom is hexacoordinated with a (C,N)(2)SnX (2) (X = Cl/Br) distorted octahedral core as a result of the strong intramolecular N→Sn coordination trans to the Sn—X bonds (N1—Sn1—X1 = 165.8°). As a result of the intermolecular contacts, viz. H⋯X and H⋯benzene interactions, the molecules are arranged in a three-dimensional supramolecular manner in the crystal structure. |
format | Text |
id | pubmed-2947775 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29477752010-12-30 Substitutional disorder in a hypervalent diorganotin(IV) dihalide Rotar, Adina Varga, Richard A. Silvestru, Cristian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of bromidochloridobis[2-(dimethylaminomethyl)phenyl]tin(IV), [SnBr(0.65)Cl(1.35)(C(9)H(12)N)(2)], contains two 2-(Me(2)NCH(2))C(6)H(4) units bonded to a Sn atom which lies on a twofold axis. The compound exhibits substitutional disorder of the halide atoms bonded to the Sn, with 1.35 occupancy for Cl and 0.65 for Br; it is isomorphous with the corresponding dichloride. The Sn atom is hexacoordinated with a (C,N)(2)SnX (2) (X = Cl/Br) distorted octahedral core as a result of the strong intramolecular N→Sn coordination trans to the Sn—X bonds (N1—Sn1—X1 = 165.8°). As a result of the intermolecular contacts, viz. H⋯X and H⋯benzene interactions, the molecules are arranged in a three-dimensional supramolecular manner in the crystal structure. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2947775/ /pubmed/21200616 http://dx.doi.org/10.1107/S1600536807063386 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Rotar, Adina Varga, Richard A. Silvestru, Cristian Substitutional disorder in a hypervalent diorganotin(IV) dihalide |
title | Substitutional disorder in a hypervalent diorganotin(IV) dihalide |
title_full | Substitutional disorder in a hypervalent diorganotin(IV) dihalide |
title_fullStr | Substitutional disorder in a hypervalent diorganotin(IV) dihalide |
title_full_unstemmed | Substitutional disorder in a hypervalent diorganotin(IV) dihalide |
title_short | Substitutional disorder in a hypervalent diorganotin(IV) dihalide |
title_sort | substitutional disorder in a hypervalent diorganotin(iv) dihalide |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2947775/ https://www.ncbi.nlm.nih.gov/pubmed/21200616 http://dx.doi.org/10.1107/S1600536807063386 |
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