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Bis(2-aminopyridine-κN (1))bis(benzoato-κO)cobalt(II)
In the title compound, [Co(C(7)H(5)O(2))(2)(C(5)H(6)N(2))(2)], the Co(II) atom is hexacoordinated by four O atoms from two benzoate anions, and two N atoms from two 2-aminopyridine molecules, resulting in a distorted octahedral geometry. Both benzoate anions act as bidentate ligands and both 2-a...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2947776/ https://www.ncbi.nlm.nih.gov/pubmed/21200656 http://dx.doi.org/10.1107/S1600536807063933 |
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author | Zhong, Di-Chang Guo, Gui-Quan Zuo, Xiao-Hua Deng, Ji-Hua Yuan, Lin Zhu, Rong-Hua |
author_facet | Zhong, Di-Chang Guo, Gui-Quan Zuo, Xiao-Hua Deng, Ji-Hua Yuan, Lin Zhu, Rong-Hua |
author_sort | Zhong, Di-Chang |
collection | PubMed |
description | In the title compound, [Co(C(7)H(5)O(2))(2)(C(5)H(6)N(2))(2)], the Co(II) atom is hexacoordinated by four O atoms from two benzoate anions, and two N atoms from two 2-aminopyridine molecules, resulting in a distorted octahedral geometry. Both benzoate anions act as bidentate ligands and both 2-aminopyridine molecules are coordinated to the metal through their pyridyl N atoms. The crystal packing is stabilized by intermolecular N—H⋯O hydrogen bonds, C—H⋯π, and π–π stacking interactions involving benzoate anions and 2-aminopyridine molecules. |
format | Text |
id | pubmed-2947776 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29477762010-12-30 Bis(2-aminopyridine-κN (1))bis(benzoato-κO)cobalt(II) Zhong, Di-Chang Guo, Gui-Quan Zuo, Xiao-Hua Deng, Ji-Hua Yuan, Lin Zhu, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(5)O(2))(2)(C(5)H(6)N(2))(2)], the Co(II) atom is hexacoordinated by four O atoms from two benzoate anions, and two N atoms from two 2-aminopyridine molecules, resulting in a distorted octahedral geometry. Both benzoate anions act as bidentate ligands and both 2-aminopyridine molecules are coordinated to the metal through their pyridyl N atoms. The crystal packing is stabilized by intermolecular N—H⋯O hydrogen bonds, C—H⋯π, and π–π stacking interactions involving benzoate anions and 2-aminopyridine molecules. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2947776/ /pubmed/21200656 http://dx.doi.org/10.1107/S1600536807063933 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Zhong, Di-Chang Guo, Gui-Quan Zuo, Xiao-Hua Deng, Ji-Hua Yuan, Lin Zhu, Rong-Hua Bis(2-aminopyridine-κN (1))bis(benzoato-κO)cobalt(II) |
title | Bis(2-aminopyridine-κN
(1))bis(benzoato-κO)cobalt(II) |
title_full | Bis(2-aminopyridine-κN
(1))bis(benzoato-κO)cobalt(II) |
title_fullStr | Bis(2-aminopyridine-κN
(1))bis(benzoato-κO)cobalt(II) |
title_full_unstemmed | Bis(2-aminopyridine-κN
(1))bis(benzoato-κO)cobalt(II) |
title_short | Bis(2-aminopyridine-κN
(1))bis(benzoato-κO)cobalt(II) |
title_sort | bis(2-aminopyridine-κn
(1))bis(benzoato-κo)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2947776/ https://www.ncbi.nlm.nih.gov/pubmed/21200656 http://dx.doi.org/10.1107/S1600536807063933 |
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