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Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II)

In the title compound, [Co(C(7)H(5)O(2))(2)(C(5)H(6)N(2))(2)], the Co(II) atom is hexa­coordinated by four O atoms from two benzoate anions, and two N atoms from two 2-amino­pyridine mol­ecules, resulting in a distorted octa­hedral geometry. Both benzoate anions act as bidentate ligands and both 2-a...

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Autores principales: Zhong, Di-Chang, Guo, Gui-Quan, Zuo, Xiao-Hua, Deng, Ji-Hua, Yuan, Lin, Zhu, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2947776/
https://www.ncbi.nlm.nih.gov/pubmed/21200656
http://dx.doi.org/10.1107/S1600536807063933
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author Zhong, Di-Chang
Guo, Gui-Quan
Zuo, Xiao-Hua
Deng, Ji-Hua
Yuan, Lin
Zhu, Rong-Hua
author_facet Zhong, Di-Chang
Guo, Gui-Quan
Zuo, Xiao-Hua
Deng, Ji-Hua
Yuan, Lin
Zhu, Rong-Hua
author_sort Zhong, Di-Chang
collection PubMed
description In the title compound, [Co(C(7)H(5)O(2))(2)(C(5)H(6)N(2))(2)], the Co(II) atom is hexa­coordinated by four O atoms from two benzoate anions, and two N atoms from two 2-amino­pyridine mol­ecules, resulting in a distorted octa­hedral geometry. Both benzoate anions act as bidentate ligands and both 2-amino­pyridine mol­ecules are coordinated to the metal through their pyridyl N atoms. The crystal packing is stabilized by inter­molecular N—H⋯O hydrogen bonds, C—H⋯π, and π–π stacking inter­actions involving benzoate anions and 2-amino­pyridine mol­ecules.
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spelling pubmed-29477762010-12-30 Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II) Zhong, Di-Chang Guo, Gui-Quan Zuo, Xiao-Hua Deng, Ji-Hua Yuan, Lin Zhu, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(5)O(2))(2)(C(5)H(6)N(2))(2)], the Co(II) atom is hexa­coordinated by four O atoms from two benzoate anions, and two N atoms from two 2-amino­pyridine mol­ecules, resulting in a distorted octa­hedral geometry. Both benzoate anions act as bidentate ligands and both 2-amino­pyridine mol­ecules are coordinated to the metal through their pyridyl N atoms. The crystal packing is stabilized by inter­molecular N—H⋯O hydrogen bonds, C—H⋯π, and π–π stacking inter­actions involving benzoate anions and 2-amino­pyridine mol­ecules. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2947776/ /pubmed/21200656 http://dx.doi.org/10.1107/S1600536807063933 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhong, Di-Chang
Guo, Gui-Quan
Zuo, Xiao-Hua
Deng, Ji-Hua
Yuan, Lin
Zhu, Rong-Hua
Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II)
title Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II)
title_full Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II)
title_fullStr Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II)
title_full_unstemmed Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II)
title_short Bis(2-amino­pyridine-κN (1))bis­(benzoato-κO)cobalt(II)
title_sort bis(2-amino­pyridine-κn (1))bis­(benzoato-κo)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2947776/
https://www.ncbi.nlm.nih.gov/pubmed/21200656
http://dx.doi.org/10.1107/S1600536807063933
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