Cargando…
Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{ N,N-bis(2-hydroxyethyl)glycinate}cadmium(II)
The reaction of N, N-bis(2-hydroxyethyl)glycine (bicine; bicH(3)) with Cd(O(2)CPh)(2) · 2H(2)O in MeOH yielded the polymeric compound [Cd(2)(O(2)CPh)(2)(bicH(2))(2)](n)(1). The complex crystallizes in the tetragonal space group P4(1)2(1)2. The lattice constants are a = b = 12.737(5) and c = 18.288(7...
Autores principales: | , , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
Hindawi Publishing Corporation
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2952795/ https://www.ncbi.nlm.nih.gov/pubmed/20976297 http://dx.doi.org/10.1155/2010/281932 |
_version_ | 1782187804834398208 |
---|---|
author | Katsoulakou, Eugenia Konidaris, Konstantis F. Raptopoulou, Catherine P. Psyharis, Vassilis Manessi-Zoupa, Evy Perlepes, Spyros P. |
author_facet | Katsoulakou, Eugenia Konidaris, Konstantis F. Raptopoulou, Catherine P. Psyharis, Vassilis Manessi-Zoupa, Evy Perlepes, Spyros P. |
author_sort | Katsoulakou, Eugenia |
collection | PubMed |
description | The reaction of N, N-bis(2-hydroxyethyl)glycine (bicine; bicH(3)) with Cd(O(2)CPh)(2) · 2H(2)O in MeOH yielded the polymeric compound [Cd(2)(O(2)CPh)(2)(bicH(2))(2)](n)(1). The complex crystallizes in the tetragonal space group P4(1)2(1)2. The lattice constants are a = b = 12.737(5) and c = 18.288(7) Å. The compound contains chains of repeating {Cd(2)(O(2)CPh)(2)(bicH(2))(2)} units. One Cd(II) atom is coordinated by two carboxylate oxygen, four hydroxyl oxygen, and two nitrogen atoms from two symmetry-related 2.21111 (Harris notation) bicH(2) (−) ligands. The other Cd(II) atom is coordinated by six carboxylate oxygen atoms, four from two bicH(2) (−) ligands and two from the monodentate benzoate groups. Each bicinate(-1) ligand chelates the 8-coordinate, square antiprismatic Cd(II) atom through one carboxylate oxygen, the nitrogen, and both hydroxyl oxygen atoms and bridges the second, six-coordinate trigonal prismatic Cd(II) center through its carboxylate oxygen atoms. Compound 1 is the first structurally characterized cadmium(II) complex containing any anionic form of bicine as ligand. IR data of 1 are discussed in terms of the coordination modes of the ligands and the known structure. |
format | Text |
id | pubmed-2952795 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | Hindawi Publishing Corporation |
record_format | MEDLINE/PubMed |
spelling | pubmed-29527952010-10-25 Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{ N,N-bis(2-hydroxyethyl)glycinate}cadmium(II) Katsoulakou, Eugenia Konidaris, Konstantis F. Raptopoulou, Catherine P. Psyharis, Vassilis Manessi-Zoupa, Evy Perlepes, Spyros P. Bioinorg Chem Appl Research Article The reaction of N, N-bis(2-hydroxyethyl)glycine (bicine; bicH(3)) with Cd(O(2)CPh)(2) · 2H(2)O in MeOH yielded the polymeric compound [Cd(2)(O(2)CPh)(2)(bicH(2))(2)](n)(1). The complex crystallizes in the tetragonal space group P4(1)2(1)2. The lattice constants are a = b = 12.737(5) and c = 18.288(7) Å. The compound contains chains of repeating {Cd(2)(O(2)CPh)(2)(bicH(2))(2)} units. One Cd(II) atom is coordinated by two carboxylate oxygen, four hydroxyl oxygen, and two nitrogen atoms from two symmetry-related 2.21111 (Harris notation) bicH(2) (−) ligands. The other Cd(II) atom is coordinated by six carboxylate oxygen atoms, four from two bicH(2) (−) ligands and two from the monodentate benzoate groups. Each bicinate(-1) ligand chelates the 8-coordinate, square antiprismatic Cd(II) atom through one carboxylate oxygen, the nitrogen, and both hydroxyl oxygen atoms and bridges the second, six-coordinate trigonal prismatic Cd(II) center through its carboxylate oxygen atoms. Compound 1 is the first structurally characterized cadmium(II) complex containing any anionic form of bicine as ligand. IR data of 1 are discussed in terms of the coordination modes of the ligands and the known structure. Hindawi Publishing Corporation 2010 2010-10-10 /pmc/articles/PMC2952795/ /pubmed/20976297 http://dx.doi.org/10.1155/2010/281932 Text en Copyright © 2010 Eugenia Katsoulakou et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Article Katsoulakou, Eugenia Konidaris, Konstantis F. Raptopoulou, Catherine P. Psyharis, Vassilis Manessi-Zoupa, Evy Perlepes, Spyros P. Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{ N,N-bis(2-hydroxyethyl)glycinate}cadmium(II) |
title | Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{
N,N-bis(2-hydroxyethyl)glycinate}cadmium(II) |
title_full | Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{
N,N-bis(2-hydroxyethyl)glycinate}cadmium(II) |
title_fullStr | Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{
N,N-bis(2-hydroxyethyl)glycinate}cadmium(II) |
title_full_unstemmed | Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{
N,N-bis(2-hydroxyethyl)glycinate}cadmium(II) |
title_short | Synthesis, X-Ray Structure, and Characterization of Catena-bis(benzoate)bis{
N,N-bis(2-hydroxyethyl)glycinate}cadmium(II) |
title_sort | synthesis, x-ray structure, and characterization of catena-bis(benzoate)bis{
n,n-bis(2-hydroxyethyl)glycinate}cadmium(ii) |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2952795/ https://www.ncbi.nlm.nih.gov/pubmed/20976297 http://dx.doi.org/10.1155/2010/281932 |
work_keys_str_mv | AT katsoulakoueugenia synthesisxraystructureandcharacterizationofcatenabisbenzoatebisnnbis2hydroxyethylglycinatecadmiumii AT konidariskonstantisf synthesisxraystructureandcharacterizationofcatenabisbenzoatebisnnbis2hydroxyethylglycinatecadmiumii AT raptopouloucatherinep synthesisxraystructureandcharacterizationofcatenabisbenzoatebisnnbis2hydroxyethylglycinatecadmiumii AT psyharisvassilis synthesisxraystructureandcharacterizationofcatenabisbenzoatebisnnbis2hydroxyethylglycinatecadmiumii AT manessizoupaevy synthesisxraystructureandcharacterizationofcatenabisbenzoatebisnnbis2hydroxyethylglycinatecadmiumii AT perlepesspyrosp synthesisxraystructureandcharacterizationofcatenabisbenzoatebisnnbis2hydroxyethylglycinatecadmiumii |