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CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF(3) and BH(3)

In situ formation of two cyclic (alkyl) (amino) carbenes (CAACs) followed by addition of BF(3)•Et(2)O provided the first two examples of CAAC–BF(3) complexes: 1-(2,6-diisopropylphenyl)-3,5,5-trimethyl-3-phenylpyrrolidin-2-ylidene trifluoroborane, and 2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro...

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Detalles Bibliográficos
Autores principales:	Monot, Julien, Fensterbank, Louis, Malacria, Max, Lacôte, Emmanuel, Geib, Steven J, Curran, Dennis P
Formato:	Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2010
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956467/ https://www.ncbi.nlm.nih.gov/pubmed/20978616 http://dx.doi.org/10.3762/bjoc.6.82

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