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Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit
A phosphorus containing dendrimer with a diphenylsilanediol core was synthesized using a divergent method. Several types of reactions were performed on dendrons of several sizes, either at the level of the core or the surface. The giant Schiff’s base macro molecule possesses 12 imine bonds and 8 hyd...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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Beilstein-Institut
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956571/ https://www.ncbi.nlm.nih.gov/pubmed/20978626 http://dx.doi.org/10.3762/bjoc.6.85 |
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author | Dadapeer, E Babu, B Hari Suresh Reddy, C Charmarthi, Naga Raju |
author_facet | Dadapeer, E Babu, B Hari Suresh Reddy, C Charmarthi, Naga Raju |
author_sort | Dadapeer, E |
collection | PubMed |
description | A phosphorus containing dendrimer with a diphenylsilanediol core was synthesized using a divergent method. Several types of reactions were performed on dendrons of several sizes, either at the level of the core or the surface. The giant Schiff’s base macro molecule possesses 12 imine bonds and 8 hydroxy groups on the terminal phenyl groups. The structures of the intermediate compounds were confirmed by IR, GCMS and (31)P NMR. The final compound was characterized by (1)H, (13)C, (31)P NMR, MALDI-TOF MS and CHN analysis. Scanning electron microscopic and thermogravimetric analysis/differential scanning calorimetric studies were also performed on the final dendritic molecule. |
format | Text |
id | pubmed-2956571 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-29565712010-10-26 Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit Dadapeer, E Babu, B Hari Suresh Reddy, C Charmarthi, Naga Raju Beilstein J Org Chem Full Research Paper A phosphorus containing dendrimer with a diphenylsilanediol core was synthesized using a divergent method. Several types of reactions were performed on dendrons of several sizes, either at the level of the core or the surface. The giant Schiff’s base macro molecule possesses 12 imine bonds and 8 hydroxy groups on the terminal phenyl groups. The structures of the intermediate compounds were confirmed by IR, GCMS and (31)P NMR. The final compound was characterized by (1)H, (13)C, (31)P NMR, MALDI-TOF MS and CHN analysis. Scanning electron microscopic and thermogravimetric analysis/differential scanning calorimetric studies were also performed on the final dendritic molecule. Beilstein-Institut 2010-08-11 /pmc/articles/PMC2956571/ /pubmed/20978626 http://dx.doi.org/10.3762/bjoc.6.85 Text en Copyright © 2010, Dadapeer et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Full Research Paper Dadapeer, E Babu, B Hari Suresh Reddy, C Charmarthi, Naga Raju Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit |
title | Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit |
title_full | Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit |
title_fullStr | Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit |
title_full_unstemmed | Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit |
title_short | Synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit |
title_sort | synthesis, spectral characterization, electron microscopic study and thermogravimetric analysis of a phosphorus containing dendrimer with diphenylsilanediol as core unit |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956571/ https://www.ncbi.nlm.nih.gov/pubmed/20978626 http://dx.doi.org/10.3762/bjoc.6.85 |
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