Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)

In the title compound, Na(+)·4C(7)H(5)N(6) (+)·5BF(4) (−), the Na(+) ion lies on a fourfold rotation axis and one of the tetra­fluoridoborate ions lies on a site of symmetry [Image: see text]. Each Na(+) ion is surrounded by four symmetry-related tetra­fluoridoborate ions, and is eight-coordinated b...

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Detalles Bibliográficos
Autores principales: Jiang, Yuqin, Hou, Yanhui, Chen, Yongsheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959227/
https://www.ncbi.nlm.nih.gov/pubmed/21201054
http://dx.doi.org/10.1107/S1600536808030286
Descripción
Sumario:In the title compound, Na(+)·4C(7)H(5)N(6) (+)·5BF(4) (−), the Na(+) ion lies on a fourfold rotation axis and one of the tetra­fluoridoborate ions lies on a site of symmetry [Image: see text]. Each Na(+) ion is surrounded by four symmetry-related tetra­fluoridoborate ions, and is eight-coordinated by F atoms, the Na⋯F separation being 2.3956 (15) or 2.4347 (17) Å. The hexa­azaphenalenium ring system is essentially planar. In the crystal structure, the cations and anions are linked into a three-dimensional network by N—H⋯N and C—H⋯F hydrogen bonds.

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