Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)

In the title compound, Na(+)·4C(7)H(5)N(6) (+)·5BF(4) (−), the Na(+) ion lies on a fourfold rotation axis and one of the tetra­fluoridoborate ions lies on a site of symmetry [Image: see text]. Each Na(+) ion is surrounded by four symmetry-related tetra­fluoridoborate ions, and is eight-coordinated b...

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Detalles Bibliográficos
Autores principales: Jiang, Yuqin, Hou, Yanhui, Chen, Yongsheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959227/
https://www.ncbi.nlm.nih.gov/pubmed/21201054
http://dx.doi.org/10.1107/S1600536808030286
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author Jiang, Yuqin
Hou, Yanhui
Chen, Yongsheng
author_facet Jiang, Yuqin
Hou, Yanhui
Chen, Yongsheng
author_sort Jiang, Yuqin
collection PubMed
description In the title compound, Na(+)·4C(7)H(5)N(6) (+)·5BF(4) (−), the Na(+) ion lies on a fourfold rotation axis and one of the tetra­fluoridoborate ions lies on a site of symmetry [Image: see text]. Each Na(+) ion is surrounded by four symmetry-related tetra­fluoridoborate ions, and is eight-coordinated by F atoms, the Na⋯F separation being 2.3956 (15) or 2.4347 (17) Å. The hexa­azaphenalenium ring system is essentially planar. In the crystal structure, the cations and anions are linked into a three-dimensional network by N—H⋯N and C—H⋯F hydrogen bonds.
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spelling pubmed-29592272010-12-30 Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate) Jiang, Yuqin Hou, Yanhui Chen, Yongsheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, Na(+)·4C(7)H(5)N(6) (+)·5BF(4) (−), the Na(+) ion lies on a fourfold rotation axis and one of the tetra­fluoridoborate ions lies on a site of symmetry [Image: see text]. Each Na(+) ion is surrounded by four symmetry-related tetra­fluoridoborate ions, and is eight-coordinated by F atoms, the Na⋯F separation being 2.3956 (15) or 2.4347 (17) Å. The hexa­azaphenalenium ring system is essentially planar. In the crystal structure, the cations and anions are linked into a three-dimensional network by N—H⋯N and C—H⋯F hydrogen bonds. International Union of Crystallography 2008-09-24 /pmc/articles/PMC2959227/ /pubmed/21201054 http://dx.doi.org/10.1107/S1600536808030286 Text en © Jiang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Yuqin
Hou, Yanhui
Chen, Yongsheng
Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)
title Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)
title_full Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)
title_fullStr Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)
title_full_unstemmed Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)
title_short Tetra­kis(1,3,4,6,7,9-hexa­aza-1H-phen­alen-6-ium) sodium(I) penta­kis(tetra­fluorido­borate)
title_sort tetra­kis(1,3,4,6,7,9-hexa­aza-1h-phen­alen-6-ium) sodium(i) penta­kis(tetra­fluorido­borate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959227/
https://www.ncbi.nlm.nih.gov/pubmed/21201054
http://dx.doi.org/10.1107/S1600536808030286
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AT chenyongsheng tetrakis134679hexaaza1hphenalen6iumsodiumipentakistetrafluoridoborate

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