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catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido]
In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyanomethanide ligands in a distorted octahedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain paral...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959235/ https://www.ncbi.nlm.nih.gov/pubmed/21201058 http://dx.doi.org/10.1107/S1600536808030377 |
Sumario: | In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyanomethanide ligands in a distorted octahedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain parallel to ([Image: see text]10). π–π Stacking interactions of terpy molecules between adjacent chains (centroid–centroid distance = 3.785 Å), along with weak intermolecular C—H⋯N hydrogen bonds involving the uncoordinated terminal N atoms of the tricyanomethanide ions and the terpyridine H atoms, result in the formation of a three-dimensional network structure. |
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