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catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido]
In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyanomethanide ligands in a distorted octahedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain paral...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959235/ https://www.ncbi.nlm.nih.gov/pubmed/21201058 http://dx.doi.org/10.1107/S1600536808030377 |
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author | Luo, Jun Zhang, Xin-Rong Dai, Wei-Quan Cui, Li-Li Liu, Bao-Shu |
author_facet | Luo, Jun Zhang, Xin-Rong Dai, Wei-Quan Cui, Li-Li Liu, Bao-Shu |
author_sort | Luo, Jun |
collection | PubMed |
description | In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyanomethanide ligands in a distorted octahedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain parallel to ([Image: see text]10). π–π Stacking interactions of terpy molecules between adjacent chains (centroid–centroid distance = 3.785 Å), along with weak intermolecular C—H⋯N hydrogen bonds involving the uncoordinated terminal N atoms of the tricyanomethanide ions and the terpyridine H atoms, result in the formation of a three-dimensional network structure. |
format | Text |
id | pubmed-2959235 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29592352010-12-30 catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido] Luo, Jun Zhang, Xin-Rong Dai, Wei-Quan Cui, Li-Li Liu, Bao-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyanomethanide ligands in a distorted octahedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain parallel to ([Image: see text]10). π–π Stacking interactions of terpy molecules between adjacent chains (centroid–centroid distance = 3.785 Å), along with weak intermolecular C—H⋯N hydrogen bonds involving the uncoordinated terminal N atoms of the tricyanomethanide ions and the terpyridine H atoms, result in the formation of a three-dimensional network structure. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959235/ /pubmed/21201058 http://dx.doi.org/10.1107/S1600536808030377 Text en © Luo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Luo, Jun Zhang, Xin-Rong Dai, Wei-Quan Cui, Li-Li Liu, Bao-Shu catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido] |
title |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido] |
title_full |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido] |
title_fullStr |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido] |
title_full_unstemmed |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido] |
title_short |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido] |
title_sort | catena-poly[[(2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)(tricyanomethanido-κn)nickel(ii)]-μ-tricyanomethanido] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959235/ https://www.ncbi.nlm.nih.gov/pubmed/21201058 http://dx.doi.org/10.1107/S1600536808030377 |
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