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catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido]

In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyano­methanide ligands in a distorted octa­hedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain paral...

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Detalles Bibliográficos
Autores principales: Luo, Jun, Zhang, Xin-Rong, Dai, Wei-Quan, Cui, Li-Li, Liu, Bao-Shu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959235/
https://www.ncbi.nlm.nih.gov/pubmed/21201058
http://dx.doi.org/10.1107/S1600536808030377
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author Luo, Jun
Zhang, Xin-Rong
Dai, Wei-Quan
Cui, Li-Li
Liu, Bao-Shu
author_facet Luo, Jun
Zhang, Xin-Rong
Dai, Wei-Quan
Cui, Li-Li
Liu, Bao-Shu
author_sort Luo, Jun
collection PubMed
description In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyano­methanide ligands in a distorted octa­hedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain parallel to ([Image: see text]10). π–π Stacking inter­actions of terpy mol­ecules between adjacent chains (centroid–centroid distance = 3.785 Å), along with weak inter­molecular C—H⋯N hydrogen bonds involving the uncoordinated terminal N atoms of the tricyanomethanide ions and the terpyridine H atoms, result in the formation of a three-dimensional network structure.
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spelling pubmed-29592352010-12-30 catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido] Luo, Jun Zhang, Xin-Rong Dai, Wei-Quan Cui, Li-Li Liu, Bao-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2′:6′2′′-terpyridine (terpy) and three tricyano­methanide ligands in a distorted octa­hedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain parallel to ([Image: see text]10). π–π Stacking inter­actions of terpy mol­ecules between adjacent chains (centroid–centroid distance = 3.785 Å), along with weak inter­molecular C—H⋯N hydrogen bonds involving the uncoordinated terminal N atoms of the tricyanomethanide ions and the terpyridine H atoms, result in the formation of a three-dimensional network structure. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959235/ /pubmed/21201058 http://dx.doi.org/10.1107/S1600536808030377 Text en © Luo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Jun
Zhang, Xin-Rong
Dai, Wei-Quan
Cui, Li-Li
Liu, Bao-Shu
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido]
title catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido]
title_full catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido]
title_fullStr catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido]
title_full_unstemmed catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido]
title_short catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyano­methanido-κN)nickel(II)]-μ-tricyano­methanido]
title_sort catena-poly[[(2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)(tricyano­methanido-κn)nickel(ii)]-μ-tricyano­methanido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959235/
https://www.ncbi.nlm.nih.gov/pubmed/21201058
http://dx.doi.org/10.1107/S1600536808030377
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