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{2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II)
In the title compound, [Ni(C(24)H(43)P(2))Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6-bis[(di-tert-butylphosphino)methyl]phenyl ligand trans to one another. The P—Ni—P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°.
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959246/ https://www.ncbi.nlm.nih.gov/pubmed/21201043 http://dx.doi.org/10.1107/S1600536808029814 |
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author | Boro, Brian J. Dickie, Diane A. Goldberg, Karen I. Kemp, Richard A. |
author_facet | Boro, Brian J. Dickie, Diane A. Goldberg, Karen I. Kemp, Richard A. |
author_sort | Boro, Brian J. |
collection | PubMed |
description | In the title compound, [Ni(C(24)H(43)P(2))Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6-bis[(di-tert-butylphosphino)methyl]phenyl ligand trans to one another. The P—Ni—P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°. |
format | Text |
id | pubmed-2959246 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29592462010-12-30 {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) Boro, Brian J. Dickie, Diane A. Goldberg, Karen I. Kemp, Richard A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(24)H(43)P(2))Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6-bis[(di-tert-butylphosphino)methyl]phenyl ligand trans to one another. The P—Ni—P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959246/ /pubmed/21201043 http://dx.doi.org/10.1107/S1600536808029814 Text en © Boro et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Boro, Brian J. Dickie, Diane A. Goldberg, Karen I. Kemp, Richard A. {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) |
title | {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) |
title_full | {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) |
title_fullStr | {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) |
title_full_unstemmed | {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) |
title_short | {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) |
title_sort | {2,6-bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959246/ https://www.ncbi.nlm.nih.gov/pubmed/21201043 http://dx.doi.org/10.1107/S1600536808029814 |
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