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{2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II)

In the title compound, [Ni(C(24)H(43)P(2))Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6-bis­[(di-tert-butyl­phosphino)meth­yl]phenyl ligand trans to one another. The P—Ni—P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°.

Detalles Bibliográficos
Autores principales: Boro, Brian J., Dickie, Diane A., Goldberg, Karen I., Kemp, Richard A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959246/
https://www.ncbi.nlm.nih.gov/pubmed/21201043
http://dx.doi.org/10.1107/S1600536808029814
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author Boro, Brian J.
Dickie, Diane A.
Goldberg, Karen I.
Kemp, Richard A.
author_facet Boro, Brian J.
Dickie, Diane A.
Goldberg, Karen I.
Kemp, Richard A.
author_sort Boro, Brian J.
collection PubMed
description In the title compound, [Ni(C(24)H(43)P(2))Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6-bis­[(di-tert-butyl­phosphino)meth­yl]phenyl ligand trans to one another. The P—Ni—P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°.
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spelling pubmed-29592462010-12-30 {2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II) Boro, Brian J. Dickie, Diane A. Goldberg, Karen I. Kemp, Richard A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(24)H(43)P(2))Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6-bis­[(di-tert-butyl­phosphino)meth­yl]phenyl ligand trans to one another. The P—Ni—P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959246/ /pubmed/21201043 http://dx.doi.org/10.1107/S1600536808029814 Text en © Boro et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boro, Brian J.
Dickie, Diane A.
Goldberg, Karen I.
Kemp, Richard A.
{2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II)
title {2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II)
title_full {2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II)
title_fullStr {2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II)
title_full_unstemmed {2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II)
title_short {2,6-Bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(II)
title_sort {2,6-bis[(di-tert-butyl­phosphino)­methyl]­phenyl}chloridonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959246/
https://www.ncbi.nlm.nih.gov/pubmed/21201043
http://dx.doi.org/10.1107/S1600536808029814
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