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2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium iodide monohydrate
In the title compound, C(14)H(13)ClN(+)·I(−)·H(2)O, the cation is nearly planar and exists in an E configuration; the dihedral angle between the pyridinium and benzene rings is 0.98 (17)°. The cations stack in an anti-parallel manner along the a axis through two π–π interactions between the pyridin...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959251/ https://www.ncbi.nlm.nih.gov/pubmed/21201095 http://dx.doi.org/10.1107/S1600536808027724 |
Sumario: | In the title compound, C(14)H(13)ClN(+)·I(−)·H(2)O, the cation is nearly planar and exists in an E configuration; the dihedral angle between the pyridinium and benzene rings is 0.98 (17)°. The cations stack in an anti-parallel manner along the a axis through two π–π interactions between the pyridinium and benzene rings [centroid–centroid distances 3.569 (2) and 3.6818 (13) Å, respectively]. The cation, anion and water molecule are linked into a chain along the a axis by weak C—H⋯O and C—H⋯I interactions together with O—H⋯I hydrogen bonds and the chains are further connected into a three-dimensional network. |
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