tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate

The relative configuration of tert-butyl 2-de­oxy-4,5-O-iso­propyl­idene-d-gluconate, C(13)H(24)O(6), an inter­mediate in the synthesis of 2-de­oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O—H⋯O hydrogen-bonded mol­ecules running parallel to th...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Booth, K. Victoria, Best, Daniel, Fleet, George W. J., Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959253/
https://www.ncbi.nlm.nih.gov/pubmed/21201208
http://dx.doi.org/10.1107/S160053680803064X
Descripción
Sumario:The relative configuration of tert-butyl 2-de­oxy-4,5-O-iso­propyl­idene-d-gluconate, C(13)H(24)O(6), an inter­mediate in the synthesis of 2-de­oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O—H⋯O hydrogen-bonded mol­ecules running parallel to the a axis. There are two mol­ecules in the asymmetric unit. The absolute configuration was inferred from the use of d-erythrono­lactone as the starting material.

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