tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate

The relative configuration of tert-butyl 2-de­oxy-4,5-O-iso­propyl­idene-d-gluconate, C(13)H(24)O(6), an inter­mediate in the synthesis of 2-de­oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O—H⋯O hydrogen-bonded mol­ecules running parallel to th...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Booth, K. Victoria, Best, Daniel, Fleet, George W. J., Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959253/
https://www.ncbi.nlm.nih.gov/pubmed/21201208
http://dx.doi.org/10.1107/S160053680803064X
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author Jenkinson, Sarah F.
Booth, K. Victoria
Best, Daniel
Fleet, George W. J.
Watkin, David J.
author_facet Jenkinson, Sarah F.
Booth, K. Victoria
Best, Daniel
Fleet, George W. J.
Watkin, David J.
author_sort Jenkinson, Sarah F.
collection PubMed
description The relative configuration of tert-butyl 2-de­oxy-4,5-O-iso­propyl­idene-d-gluconate, C(13)H(24)O(6), an inter­mediate in the synthesis of 2-de­oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O—H⋯O hydrogen-bonded mol­ecules running parallel to the a axis. There are two mol­ecules in the asymmetric unit. The absolute configuration was inferred from the use of d-erythrono­lactone as the starting material.
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spelling pubmed-29592532010-12-30 tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate Jenkinson, Sarah F. Booth, K. Victoria Best, Daniel Fleet, George W. J. Watkin, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The relative configuration of tert-butyl 2-de­oxy-4,5-O-iso­propyl­idene-d-gluconate, C(13)H(24)O(6), an inter­mediate in the synthesis of 2-de­oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O—H⋯O hydrogen-bonded mol­ecules running parallel to the a axis. There are two mol­ecules in the asymmetric unit. The absolute configuration was inferred from the use of d-erythrono­lactone as the starting material. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959253/ /pubmed/21201208 http://dx.doi.org/10.1107/S160053680803064X Text en © Jenkinson et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jenkinson, Sarah F.
Booth, K. Victoria
Best, Daniel
Fleet, George W. J.
Watkin, David J.
tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate
title tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate
title_full tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate
title_fullStr tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate
title_full_unstemmed tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate
title_short tert-Butyl 2-de­oxy-4,5-O-isopropyl­idene-d-gluconate
title_sort tert-butyl 2-de­oxy-4,5-o-isopropyl­idene-d-gluconate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959253/
https://www.ncbi.nlm.nih.gov/pubmed/21201208
http://dx.doi.org/10.1107/S160053680803064X
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