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N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine

The mol­ecule of the title Schiff base compound, C(16)H(12)Br(2)F(2)N(2), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bonds. The imino groups are coplanar with the aromatic rings. Within the mol­ecule, the planar units are parallel...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959256/
https://www.ncbi.nlm.nih.gov/pubmed/21201147
http://dx.doi.org/10.1107/S1600536808029000
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author Fun, Hoong-Kun
Kia, Reza
author_facet Fun, Hoong-Kun
Kia, Reza
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title Schiff base compound, C(16)H(12)Br(2)F(2)N(2), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bonds. The imino groups are coplanar with the aromatic rings. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the dimethyl­ene bridge. An inter­esting feature of the crystal structure is the short inter­molecular Br⋯F inter­actions [3.2347 (16) Å, which is shorter than the sum of the van der Waals radii of these atoms]. These inter­actions link neighbouring mol­ecules along the c axis. The crystal structure is further stabilized by inter­molecular C—H⋯N hydrogen bonds.
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spelling pubmed-29592562010-12-30 N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine Fun, Hoong-Kun Kia, Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title Schiff base compound, C(16)H(12)Br(2)F(2)N(2), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bonds. The imino groups are coplanar with the aromatic rings. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the dimethyl­ene bridge. An inter­esting feature of the crystal structure is the short inter­molecular Br⋯F inter­actions [3.2347 (16) Å, which is shorter than the sum of the van der Waals radii of these atoms]. These inter­actions link neighbouring mol­ecules along the c axis. The crystal structure is further stabilized by inter­molecular C—H⋯N hydrogen bonds. International Union of Crystallography 2008-09-13 /pmc/articles/PMC2959256/ /pubmed/21201147 http://dx.doi.org/10.1107/S1600536808029000 Text en © Fun and Kia 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kia, Reza
N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine
title N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine
title_full N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine
title_fullStr N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine
title_full_unstemmed N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine
title_short N,N′-Bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine
title_sort n,n′-bis(4-bromo-2-fluoro­benzyl­idene)ethane-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959256/
https://www.ncbi.nlm.nih.gov/pubmed/21201147
http://dx.doi.org/10.1107/S1600536808029000
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