{Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II)

In the title compound, [Pd(C(37)H(55)P(2)Si)Cl], the Pd atom has a distorted square-planar geometry. The two five-membered rings adopt envelope conformations, while the four cyclo­hexane rings have chair conformations. The two planar aromatic rings are oriented at a dihedral angle of 28.79 (3)°.

Detalles Bibliográficos
Autores principales: Li, Yong-Hua, Zhang, Yuan, Zhao, Min-Min, Yuan, Yu-Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959264/
https://www.ncbi.nlm.nih.gov/pubmed/21201022
http://dx.doi.org/10.1107/S1600536808028961
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author Li, Yong-Hua
Zhang, Yuan
Zhao, Min-Min
Yuan, Yu-Yu
author_facet Li, Yong-Hua
Zhang, Yuan
Zhao, Min-Min
Yuan, Yu-Yu
author_sort Li, Yong-Hua
collection PubMed
description In the title compound, [Pd(C(37)H(55)P(2)Si)Cl], the Pd atom has a distorted square-planar geometry. The two five-membered rings adopt envelope conformations, while the four cyclo­hexane rings have chair conformations. The two planar aromatic rings are oriented at a dihedral angle of 28.79 (3)°.
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spelling pubmed-29592642010-12-30 {Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II) Li, Yong-Hua Zhang, Yuan Zhao, Min-Min Yuan, Yu-Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(37)H(55)P(2)Si)Cl], the Pd atom has a distorted square-planar geometry. The two five-membered rings adopt envelope conformations, while the four cyclo­hexane rings have chair conformations. The two planar aromatic rings are oriented at a dihedral angle of 28.79 (3)°. International Union of Crystallography 2008-09-17 /pmc/articles/PMC2959264/ /pubmed/21201022 http://dx.doi.org/10.1107/S1600536808028961 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yong-Hua
Zhang, Yuan
Zhao, Min-Min
Yuan, Yu-Yu
{Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II)
title {Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II)
title_full {Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II)
title_fullStr {Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II)
title_full_unstemmed {Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II)
title_short {Bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridopalladium(II)
title_sort {bis[2-(dicyclo­hexyl­phosphino)­phen­yl]methyl­silyl-κ(3) p,si,p′}chloridopalladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959264/
https://www.ncbi.nlm.nih.gov/pubmed/21201022
http://dx.doi.org/10.1107/S1600536808028961
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AT zhaominmin bis2dicyclohexylphosphinophenylmethylsilylk3psipchloridopalladiumii
AT yuanyuyu bis2dicyclohexylphosphinophenylmethylsilylk3psipchloridopalladiumii

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