{Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II)

In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo­hexyl; cod = cyclo­octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a tran...

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Detalles Bibliográficos
Autores principales: Li, Yong-Hua, Zhang, Yuan, Zhao, Min-Min, Li, Xian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959269/
https://www.ncbi.nlm.nih.gov/pubmed/21201023
http://dx.doi.org/10.1107/S1600536808028857
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author Li, Yong-Hua
Zhang, Yuan
Zhao, Min-Min
Li, Xian
author_facet Li, Yong-Hua
Zhang, Yuan
Zhao, Min-Min
Li, Xian
author_sort Li, Yong-Hua
collection PubMed
description In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo­hexyl; cod = cyclo­octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclo­hexane rings adopt a chair conformation.
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spelling pubmed-29592692010-12-30 {Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II) Li, Yong-Hua Zhang, Yuan Zhao, Min-Min Li, Xian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo­hexyl; cod = cyclo­octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclo­hexane rings adopt a chair conformation. International Union of Crystallography 2008-09-17 /pmc/articles/PMC2959269/ /pubmed/21201023 http://dx.doi.org/10.1107/S1600536808028857 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yong-Hua
Zhang, Yuan
Zhao, Min-Min
Li, Xian
{Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II)
title {Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II)
title_full {Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II)
title_fullStr {Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II)
title_full_unstemmed {Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II)
title_short {Bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) P,Si,P′}chloridoplatinum(II)
title_sort {bis[2-(dicyclo­hexyl­phosphino)phen­yl]methyl­silyl-κ(3) p,si,p′}chloridoplatinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959269/
https://www.ncbi.nlm.nih.gov/pubmed/21201023
http://dx.doi.org/10.1107/S1600536808028857
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AT zhangyuan bis2dicyclohexylphosphinophenylmethylsilylk3psipchloridoplatinumii
AT zhaominmin bis2dicyclohexylphosphinophenylmethylsilylk3psipchloridoplatinumii
AT lixian bis2dicyclohexylphosphinophenylmethylsilylk3psipchloridoplatinumii

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