catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]

The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2′-bipyridine, forming a slightly distorted octa­hedral geometry. Oxlate acts as a bridge to link neighbouring pa...

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Detalles Bibliográficos
Autores principales: Li, Sheng, Yan, Xing-Lian, Wang, Shou-Bin, Ma, Yuan-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959270/
https://www.ncbi.nlm.nih.gov/pubmed/21201013
http://dx.doi.org/10.1107/S1600536808028389
Descripción
Sumario:The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2′-bipyridine, forming a slightly distorted octa­hedral geometry. Oxlate acts as a bridge to link neighbouring pairs of Ni(II) cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning.

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