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catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2′-bipyridine, forming a slightly distorted octahedral geometry. Oxlate acts as a bridge to link neighbouring pa...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959270/ https://www.ncbi.nlm.nih.gov/pubmed/21201013 http://dx.doi.org/10.1107/S1600536808028389 |
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author | Li, Sheng Yan, Xing-Lian Wang, Shou-Bin Ma, Yuan-Fang |
author_facet | Li, Sheng Yan, Xing-Lian Wang, Shou-Bin Ma, Yuan-Fang |
author_sort | Li, Sheng |
collection | PubMed |
description | The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2′-bipyridine, forming a slightly distorted octahedral geometry. Oxlate acts as a bridge to link neighbouring pairs of Ni(II) cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning. |
format | Text |
id | pubmed-2959270 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29592702010-12-30 catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] Li, Sheng Yan, Xing-Lian Wang, Shou-Bin Ma, Yuan-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2′-bipyridine, forming a slightly distorted octahedral geometry. Oxlate acts as a bridge to link neighbouring pairs of Ni(II) cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning. International Union of Crystallography 2008-09-13 /pmc/articles/PMC2959270/ /pubmed/21201013 http://dx.doi.org/10.1107/S1600536808028389 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Sheng Yan, Xing-Lian Wang, Shou-Bin Ma, Yuan-Fang catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] |
title |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
title_full |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
title_fullStr |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
title_full_unstemmed |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
title_short |
catena-Poly[[(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
title_sort | catena-poly[[(2,2′-bipyridine-κ(2)
n,n′)nickel(ii)]-μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959270/ https://www.ncbi.nlm.nih.gov/pubmed/21201013 http://dx.doi.org/10.1107/S1600536808028389 |
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