2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide

In the title compound, C(16)H(19)NOS, the durene ring and the oxopyridyl ring form a dihedral angle of 82.26 (7)°. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds, weak C—H⋯π inter­actions and π–π inter­actions [centroid–centroid distance of 3.4432 (19) Å], together with...

Descripción completa

Detalles Bibliográficos
Autores principales: Ravindran Durai Nayagam, B., Jebas, Samuel Robinson, Jebaraj Devadasan, J., Schollmeyer, Dieter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959274/
https://www.ncbi.nlm.nih.gov/pubmed/21201175
http://dx.doi.org/10.1107/S1600536808029747
_version_ 1782188459874582528
author Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Jebaraj Devadasan, J.
Schollmeyer, Dieter
author_facet Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Jebaraj Devadasan, J.
Schollmeyer, Dieter
author_sort Ravindran Durai Nayagam, B.
collection PubMed
description In the title compound, C(16)H(19)NOS, the durene ring and the oxopyridyl ring form a dihedral angle of 82.26 (7)°. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds, weak C—H⋯π inter­actions and π–π inter­actions [centroid–centroid distance of 3.4432 (19) Å], together with intra­molecular S⋯O [2.657 (2) Å] short contacts.
format Text
id pubmed-2959274
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29592742010-12-30 2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide Ravindran Durai Nayagam, B. Jebas, Samuel Robinson Jebaraj Devadasan, J. Schollmeyer, Dieter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(19)NOS, the durene ring and the oxopyridyl ring form a dihedral angle of 82.26 (7)°. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds, weak C—H⋯π inter­actions and π–π inter­actions [centroid–centroid distance of 3.4432 (19) Å], together with intra­molecular S⋯O [2.657 (2) Å] short contacts. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959274/ /pubmed/21201175 http://dx.doi.org/10.1107/S1600536808029747 Text en © Ravindran Durai Nayagam et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Jebaraj Devadasan, J.
Schollmeyer, Dieter
2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide
title 2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide
title_full 2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide
title_fullStr 2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide
title_full_unstemmed 2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide
title_short 2-(2,3,5,6-Tetra­methyl­benzyl­sulfan­yl)pyridine N-oxide
title_sort 2-(2,3,5,6-tetra­methyl­benzyl­sulfan­yl)pyridine n-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959274/
https://www.ncbi.nlm.nih.gov/pubmed/21201175
http://dx.doi.org/10.1107/S1600536808029747
work_keys_str_mv AT ravindrandurainayagamb 22356tetramethylbenzylsulfanylpyridinenoxide
AT jebassamuelrobinson 22356tetramethylbenzylsulfanylpyridinenoxide
AT jebarajdevadasanj 22356tetramethylbenzylsulfanylpyridinenoxide
AT schollmeyerdieter 22356tetramethylbenzylsulfanylpyridinenoxide

Ejemplares similares