Chlorido(2-chloro­nicotinato)triphenyl­anti­mony(V)

In the title complex, [Sb(C(6)H(5))(3)(C(6)H(3)ClNO(2))Cl], the Sb center has a close to ideal trigonal-bipyramidal geometry, with the phenyl ligands in equatorial positions and the chloride and a carboxyl­ate O atom in axial positions. Weak C—H⋯O contacts generate dimeric units via crystallographic...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959277/
https://www.ncbi.nlm.nih.gov/pubmed/21201041
http://dx.doi.org/10.1107/S1600536808029632
Descripción
Sumario:In the title complex, [Sb(C(6)H(5))(3)(C(6)H(3)ClNO(2))Cl], the Sb center has a close to ideal trigonal-bipyramidal geometry, with the phenyl ligands in equatorial positions and the chloride and a carboxyl­ate O atom in axial positions. Weak C—H⋯O contacts generate dimeric units via crystallographic inversion centres.

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