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(2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride
In the racemic hydrochloride salt of the title ester, C(19)H(22)Cl(2)NO(2) (+)·Cl(−), the pentanoic acid chain shows a mixture of trans and gauche orientations to give an overall helical conformation. The dihedral angle between the two aromatic rings is 26.11 (10)°. The charged secondary amine fun...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959283/ https://www.ncbi.nlm.nih.gov/pubmed/21201230 http://dx.doi.org/10.1107/S1600536808030742 |
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| author | Kaupang, Åsmund Bolsønes, Marianne Gamadeku, Thywill Hansen, Tore Hennum, Martin Johanson Görbitz, Carl Henrik |
| author_facet | Kaupang, Åsmund Bolsønes, Marianne Gamadeku, Thywill Hansen, Tore Hennum, Martin Johanson Görbitz, Carl Henrik |
| author_sort | Kaupang, Åsmund |
| collection | PubMed |
| description | In the racemic hydrochloride salt of the title ester, C(19)H(22)Cl(2)NO(2) (+)·Cl(−), the pentanoic acid chain shows a mixture of trans and gauche orientations to give an overall helical conformation. The dihedral angle between the two aromatic rings is 26.11 (10)°. The charged secondary amine function participates in two N—H⋯Cl hydrogen bonds. |
| format | Text |
| id | pubmed-2959283 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29592832010-12-30 (2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride Kaupang, Åsmund Bolsønes, Marianne Gamadeku, Thywill Hansen, Tore Hennum, Martin Johanson Görbitz, Carl Henrik Acta Crystallogr Sect E Struct Rep Online Organic Papers In the racemic hydrochloride salt of the title ester, C(19)H(22)Cl(2)NO(2) (+)·Cl(−), the pentanoic acid chain shows a mixture of trans and gauche orientations to give an overall helical conformation. The dihedral angle between the two aromatic rings is 26.11 (10)°. The charged secondary amine function participates in two N—H⋯Cl hydrogen bonds. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959283/ /pubmed/21201230 http://dx.doi.org/10.1107/S1600536808030742 Text en © Kaupang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Kaupang, Åsmund Bolsønes, Marianne Gamadeku, Thywill Hansen, Tore Hennum, Martin Johanson Görbitz, Carl Henrik (2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride |
| title | (2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride |
| title_full | (2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride |
| title_fullStr | (2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride |
| title_full_unstemmed | (2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride |
| title_short | (2SR,3RS)-Benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride |
| title_sort | (2sr,3rs)-benzyl[4-chloro-1-(4-chlorophenyl)-1-methoxycarbonyl-2-butyl]ammonium chloride |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959283/ https://www.ncbi.nlm.nih.gov/pubmed/21201230 http://dx.doi.org/10.1107/S1600536808030742 |
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