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catena-Poly[cadmium(II)-μ-benzene-1,2-diamine-κ(2) N:N′-di-μ-chlorido]

The title compound, [CdCl(2)(C(6)H(8)N(2))](n), is a coordination polymer prepared by the hydro­thermal reaction of cadmium chloride and o-diamino­benzene. The cadmium cation, located on an inversion center, is octa­hedrally coordinated by four Cl atoms at equatorial sites and two N atoms from two l...

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Detalles Bibliográficos
Autores principales: Liang, Wen-Xian, Qu, Zhi-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959288/
https://www.ncbi.nlm.nih.gov/pubmed/21201010
http://dx.doi.org/10.1107/S1600536808027980
Descripción
Sumario:The title compound, [CdCl(2)(C(6)H(8)N(2))](n), is a coordination polymer prepared by the hydro­thermal reaction of cadmium chloride and o-diamino­benzene. The cadmium cation, located on an inversion center, is octa­hedrally coordinated by four Cl atoms at equatorial sites and two N atoms from two ligands at the axial sites. Cd atoms are bridged by Cl atoms, forming extended chains parallel to [010]. Neighboring chains are connected by N—H⋯Cl hydrogen bonds.