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Poly[diaqua(μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′))(μ(2)-pyrazine-2-carboxyl­ato-κ(3) N (1),O:O′)cerium(III)]

In the hydro­thermally synthesized title compound, [Ce(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the Ce(III) ion is coordinated by four O atoms from two different oxalate ligands, three O atoms from two symmetry-related pyrazine-2-carboxyl­ate ligands, two O atoms from two water melecules and one N...

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Detalles Bibliográficos
Autores principales: Wang, Yuanlan, Wang, Chongchen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959293/
https://www.ncbi.nlm.nih.gov/pubmed/21201029
http://dx.doi.org/10.1107/S1600536808029164
Descripción
Sumario:In the hydro­thermally synthesized title compound, [Ce(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the Ce(III) ion is coordinated by four O atoms from two different oxalate ligands, three O atoms from two symmetry-related pyrazine-2-carboxyl­ate ligands, two O atoms from two water melecules and one N atom from a pyrazine-2-carboxyl­ate ligand in a distorted bicapped square-anti­prismatic coordination geometry. The oxalate and pyrazine-2-carboxyl­ate ligands bridge the Ce(III) ions, forming a two-dimensional structure. In addition, inter­molecular O—H⋯O and O—H⋯N hydrogen bonds connect the two-dimensional structure into a three-dimensional network.