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N,N′-Bis(5-bromo-2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine
The crystal structure of the title Schiff base compound, C(19)H(20)Br(2)N(2)O(2), contains two crystallographically independent molecules (A and B) in the asymmetric unit, with similar conformations. Intramolecular O—H⋯N (× 4) and C—H⋯N (× 5) hydrogen bonds form six- and five-membered rings, produ...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959295/ https://www.ncbi.nlm.nih.gov/pubmed/21201107 http://dx.doi.org/10.1107/S160053680802816X |
Sumario: | The crystal structure of the title Schiff base compound, C(19)H(20)Br(2)N(2)O(2), contains two crystallographically independent molecules (A and B) in the asymmetric unit, with similar conformations. Intramolecular O—H⋯N (× 4) and C—H⋯N (× 5) hydrogen bonds form six- and five-membered rings, producing S(6) and S(5) ring motifs, respectively. One of the N atoms in molecule A acts as a trifurcated acceptor, the rest of the N atoms being bifurcated acceptors. The dihedral angles between the benzene rings in molecules A and B are 47.83 (17) and 61.11 (17)°, respectively. The molecular conformation is stabilized by intramolecular O—H⋯N and C—H⋯N hydrogen bonds. The short distances between the centroids of the benzene rings [3.7799 (19)–3.890 (2) Å] indicate the existence of π–π interactions. In addition, the crystal structure is further stabilized by an intermolecular C—H⋯O hydrogen bond, C—H⋯π interactions, and short intermolecular Br⋯Br and Br⋯O contacts [3.4786 (5) and 3.149 (3) Å, respectively]. |
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