Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II)

In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa­hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the cry...

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Autor principal: Yang, Zhong Nian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959305/
https://www.ncbi.nlm.nih.gov/pubmed/21201079
http://dx.doi.org/10.1107/S1600536808030882
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author Yang, Zhong Nian
author_facet Yang, Zhong Nian
author_sort Yang, Zhong Nian
collection PubMed
description In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa­hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, inter­molecular O—H⋯N and O—H⋯S hydrogen bonds link complex mol­ecules into a three-dimensional network.
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spelling pubmed-29593052010-12-30 Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II) Yang, Zhong Nian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa­hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, inter­molecular O—H⋯N and O—H⋯S hydrogen bonds link complex mol­ecules into a three-dimensional network. International Union of Crystallography 2008-09-30 /pmc/articles/PMC2959305/ /pubmed/21201079 http://dx.doi.org/10.1107/S1600536808030882 Text en © Zhong Nian Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Zhong Nian
Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II)
title Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II)
title_full Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II)
title_fullStr Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II)
title_short Diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κN (4)]bis­(thio­cyanato-κN)cobalt(II)
title_sort diaqua­bis[2-(2-pyridylmeth­oxy)pyrazine-κn (4)]bis­(thio­cyanato-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959305/
https://www.ncbi.nlm.nih.gov/pubmed/21201079
http://dx.doi.org/10.1107/S1600536808030882
work_keys_str_mv AT yangzhongnian diaquabis22pyridylmethoxypyrazinekn4bisthiocyanatokncobaltii

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