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7-Dimethyl­amino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate

7-Dimethyl­amino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine crystallized with one mol­ecule of methanol to give the title compound, C(12)H(13)N(7)·CH(3)OH. The triazolo[1,5-a][1,3,5]triazine heterocyclic core is essentially planar as are both amino groups that are involved in π-electron de...

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Detalles Bibliográficos
Autores principales: Dolzhenko, Anton V., Tan, Geok Kheng, Koh, Lip Lin, Woo, Su Fen, Chui, Wai Keung
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959306/
https://www.ncbi.nlm.nih.gov/pubmed/21201215
http://dx.doi.org/10.1107/S1600536808030481
Descripción
Sumario:7-Dimethyl­amino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine crystallized with one mol­ecule of methanol to give the title compound, C(12)H(13)N(7)·CH(3)OH. The triazolo[1,5-a][1,3,5]triazine heterocyclic core is essentially planar as are both amino groups that are involved in π-electron delocalization with the triazolo[1,5-a][1,3,5]triazine nucleus. The methyl groups of the dimethyl­amino fragment are involved in the formation of weak intra­molecular C—H⋯N hydrogen bonds with the N atoms of the heterocyclic system. The crystal packing is stabilized by inter­molecular N—H⋯N hydrogen bonds between the triazolo[1,5-a][1,3,5]triazine mol­ecules. The methanol solvent mol­ecule also participates in the formation of the crystal structure via inter­molecular O—H⋯N, N—H⋯O and weak C—H⋯O hydrogen bonds, linking the layers of triazolo[1,5-a][1,3,5]triazine mol­ecules.