Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate

The title compound, [Zn(2)Cl(4)(C(12)H(14)N(4))(2)]·2C(3)H(7)NO, is located on a centre of inversion with one half of a complex mol­ecule and one dimethyl­formamide solvent mol­ecule in the asymmetric unit. The Zn(II) ion is tetra­hedrally coordinated by two organic ligands and two chloride ions. Ea...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Zhang, Ya-Wen, Sun, Yan-Yan, Zhang, Gong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959326/
https://www.ncbi.nlm.nih.gov/pubmed/21200995
http://dx.doi.org/10.1107/S1600536808027773
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author Cheng, Lin
Zhang, Ya-Wen
Sun, Yan-Yan
Zhang, Gong
author_facet Cheng, Lin
Zhang, Ya-Wen
Sun, Yan-Yan
Zhang, Gong
author_sort Cheng, Lin
collection PubMed
description The title compound, [Zn(2)Cl(4)(C(12)H(14)N(4))(2)]·2C(3)H(7)NO, is located on a centre of inversion with one half of a complex mol­ecule and one dimethyl­formamide solvent mol­ecule in the asymmetric unit. The Zn(II) ion is tetra­hedrally coordinated by two organic ligands and two chloride ions. Each organic ligand acts as a bidentate ligand, connecting two Zn(II) ions, resulting in a dimeric [2:2] metallamacrocyclic structure. Adjacent mol­ecules are further linked by N—H⋯Cl hydrogen bonds and the solvent is linked to the complex by N—H⋯O hydrogen bonds.
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spelling pubmed-29593262010-12-30 Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate Cheng, Lin Zhang, Ya-Wen Sun, Yan-Yan Zhang, Gong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(2)Cl(4)(C(12)H(14)N(4))(2)]·2C(3)H(7)NO, is located on a centre of inversion with one half of a complex mol­ecule and one dimethyl­formamide solvent mol­ecule in the asymmetric unit. The Zn(II) ion is tetra­hedrally coordinated by two organic ligands and two chloride ions. Each organic ligand acts as a bidentate ligand, connecting two Zn(II) ions, resulting in a dimeric [2:2] metallamacrocyclic structure. Adjacent mol­ecules are further linked by N—H⋯Cl hydrogen bonds and the solvent is linked to the complex by N—H⋯O hydrogen bonds. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959326/ /pubmed/21200995 http://dx.doi.org/10.1107/S1600536808027773 Text en © Cheng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Lin
Zhang, Ya-Wen
Sun, Yan-Yan
Zhang, Gong
Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
title Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
title_full Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
title_fullStr Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
title_full_unstemmed Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
title_short Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
title_sort bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ(2) n:n′]bis[dichloridozinc(ii)] n,n′-dimethylformamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959326/
https://www.ncbi.nlm.nih.gov/pubmed/21200995
http://dx.doi.org/10.1107/S1600536808027773
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