(2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II)

In the title complex, [Ni(C(15)H(11)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole mol­ecule, forming a distorted square-planar geometry. Inter­molecular N—H⋯N hydrogen bonds li...

Descripción completa

Detalles Bibliográficos
Autor principal: Chen, Xiao-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959330/
https://www.ncbi.nlm.nih.gov/pubmed/21201009
http://dx.doi.org/10.1107/S1600536808028171
_version_ 1782188473738854400
author Chen, Xiao-Hua
author_facet Chen, Xiao-Hua
author_sort Chen, Xiao-Hua
collection PubMed
description In the title complex, [Ni(C(15)H(11)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole mol­ecule, forming a distorted square-planar geometry. Inter­molecular N—H⋯N hydrogen bonds link neighboring molecules into extended chains parallel to [100].
format Text
id pubmed-2959330
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29593302010-12-30 (2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II) Chen, Xiao-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(15)H(11)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole mol­ecule, forming a distorted square-planar geometry. Inter­molecular N—H⋯N hydrogen bonds link neighboring molecules into extended chains parallel to [100]. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959330/ /pubmed/21201009 http://dx.doi.org/10.1107/S1600536808028171 Text en © Xiao-Hua Chen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Xiao-Hua
(2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II)
title (2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II)
title_full (2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II)
title_fullStr (2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II)
title_full_unstemmed (2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II)
title_short (2-{[2-(4-Chlorophenoxy)-1-oxido­ethyl­idene-κO (1)]hydrazono­methyl}­phenol­ato-κ(2) N (1),O)(1H-imidazole-κN (3))nickel(II)
title_sort (2-{[2-(4-chlorophenoxy)-1-oxido­ethyl­idene-κo (1)]hydrazono­methyl}­phenol­ato-κ(2) n (1),o)(1h-imidazole-κn (3))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959330/
https://www.ncbi.nlm.nih.gov/pubmed/21201009
http://dx.doi.org/10.1107/S1600536808028171
work_keys_str_mv AT chenxiaohua 224chlorophenoxy1oxidoethylideneko1hydrazonomethylphenolatok2n1o1himidazolekn3nickelii

Ejemplares similares