Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate]

In the crystal structure of the title compound, {[Cu(C(8)H(6)O(9))(C(12)H(8)N(2))]·0.69H(2)O}(n), the Cu(II) atom has a distorted octa­hedral geometry, coordinated by four O atoms from two 3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ate ligands and two N atoms from one 1,10-phenanthroline ligand....

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Detalles Bibliográficos
Autor principal: Lü, Yuanqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959334/
https://www.ncbi.nlm.nih.gov/pubmed/21201002
http://dx.doi.org/10.1107/S1600536808027918
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author Lü, Yuanqi
author_facet Lü, Yuanqi
author_sort Lü, Yuanqi
collection PubMed
description In the crystal structure of the title compound, {[Cu(C(8)H(6)O(9))(C(12)H(8)N(2))]·0.69H(2)O}(n), the Cu(II) atom has a distorted octa­hedral geometry, coordinated by four O atoms from two 3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the carboxylate groups bridges the Cu(II) atoms, forming a zigzag chain running along the b axis. The chains are linked by a π–π inter­action between aromatic rings with a centroid-to-centroid distance of 3.567 (1) Å, and by hydrogen bonds between the carboxyl­ate group and the disordered water mol­ecule, forming a three-dimensional network.
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spelling pubmed-29593342010-12-30 Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate] Lü, Yuanqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, {[Cu(C(8)H(6)O(9))(C(12)H(8)N(2))]·0.69H(2)O}(n), the Cu(II) atom has a distorted octa­hedral geometry, coordinated by four O atoms from two 3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the carboxylate groups bridges the Cu(II) atoms, forming a zigzag chain running along the b axis. The chains are linked by a π–π inter­action between aromatic rings with a centroid-to-centroid distance of 3.567 (1) Å, and by hydrogen bonds between the carboxyl­ate group and the disordered water mol­ecule, forming a three-dimensional network. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959334/ /pubmed/21201002 http://dx.doi.org/10.1107/S1600536808027918 Text en © Yuanqi Lü 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lü, Yuanqi
Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate]
title Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate]
title_full Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate]
title_fullStr Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate]
title_full_unstemmed Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate]
title_short Poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2),O (5):O (2′))(1,10-phenanthroline-κ(2) N,N′)copper(II)] 0.69-hydrate]
title_sort poly[[(μ-3,4-dicarboxy­tetra­hydro­furan-2,5-dicarboxyl­ato-κ(4) o (1),o (2),o (5):o (2′))(1,10-phenanthroline-κ(2) n,n′)copper(ii)] 0.69-hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959334/
https://www.ncbi.nlm.nih.gov/pubmed/21201002
http://dx.doi.org/10.1107/S1600536808027918
work_keys_str_mv AT luyuanqi polym34dicarboxytetrahydrofuran25dicarboxylatok4o1o2o5o2110phenanthrolinek2nncopperii069hydrate

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