Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)]

In the title centrosymmetric complex, [Ag(2)(ClO(4))(2)(C(10)H(7)N(3))(2)], the unique Ag(I) ion is coordinated by an N atom from a carbonitrile group, an N atom from a symmetry-related pyrazole group and an O atom of a perchlorate ligand to form a distorted T-shaped environment. Two 3-(1H-pyrazol-1...

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Autores principales: Niu, Cao-Yuan, Zhang, Hai-Yan, Feng, Cao-Ling, Wan, Xin-Sheng, Kou, Chun-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959349/
https://www.ncbi.nlm.nih.gov/pubmed/21201066
http://dx.doi.org/10.1107/S1600536808030602
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author Niu, Cao-Yuan
Zhang, Hai-Yan
Feng, Cao-Ling
Wan, Xin-Sheng
Kou, Chun-Hong
author_facet Niu, Cao-Yuan
Zhang, Hai-Yan
Feng, Cao-Ling
Wan, Xin-Sheng
Kou, Chun-Hong
author_sort Niu, Cao-Yuan
collection PubMed
description In the title centrosymmetric complex, [Ag(2)(ClO(4))(2)(C(10)H(7)N(3))(2)], the unique Ag(I) ion is coordinated by an N atom from a carbonitrile group, an N atom from a symmetry-related pyrazole group and an O atom of a perchlorate ligand to form a distorted T-shaped environment. Two 3-(1H-pyrazol-1-yl)benzonitrile ligands each bridge two Ag(I) ions to form a dinuclear complex. In the crystal structure, there are weak Ag⋯O inter­actions within the range 2.70–3.01 Å linking dimeric units into layers approximately parallel to (100). The O atoms of the perchlorate ligand are disordered over two sites with occupancies of 0.570 (11) and 0.430 (11), respectively.
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spelling pubmed-29593492010-12-30 Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)] Niu, Cao-Yuan Zhang, Hai-Yan Feng, Cao-Ling Wan, Xin-Sheng Kou, Chun-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric complex, [Ag(2)(ClO(4))(2)(C(10)H(7)N(3))(2)], the unique Ag(I) ion is coordinated by an N atom from a carbonitrile group, an N atom from a symmetry-related pyrazole group and an O atom of a perchlorate ligand to form a distorted T-shaped environment. Two 3-(1H-pyrazol-1-yl)benzonitrile ligands each bridge two Ag(I) ions to form a dinuclear complex. In the crystal structure, there are weak Ag⋯O inter­actions within the range 2.70–3.01 Å linking dimeric units into layers approximately parallel to (100). The O atoms of the perchlorate ligand are disordered over two sites with occupancies of 0.570 (11) and 0.430 (11), respectively. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959349/ /pubmed/21201066 http://dx.doi.org/10.1107/S1600536808030602 Text en © Niu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Niu, Cao-Yuan
Zhang, Hai-Yan
Feng, Cao-Ling
Wan, Xin-Sheng
Kou, Chun-Hong
Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)]
title Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)]
title_full Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)]
title_fullStr Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)]
title_full_unstemmed Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)]
title_short Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κ(2) N:N′]bis­[perchloratosilver(I)]
title_sort bis[μ-3-(1h-pyrazol-1-yl)benzonitrile-κ(2) n:n′]bis­[perchloratosilver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959349/
https://www.ncbi.nlm.nih.gov/pubmed/21201066
http://dx.doi.org/10.1107/S1600536808030602
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