Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)

The title compound, [ZrW(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)] or [W(CO)(5)C(CH(3))OZr(C(5)H(5))(2)Cl], consists of two metal centres, with a (tungsten penta­carbon­yl)oxymethyl­carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol­ecule are related by...

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Detalles Bibliográficos
Autores principales: Esterhuysen, Catharine, Neveling, Arno, Luruli, Nyambeni, Kruger, Gert J., Cronje, Stephanie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959354/
https://www.ncbi.nlm.nih.gov/pubmed/21201008
http://dx.doi.org/10.1107/S1600536808028006
Descripción
Sumario:The title compound, [ZrW(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)] or [W(CO)(5)C(CH(3))OZr(C(5)H(5))(2)Cl], consists of two metal centres, with a (tungsten penta­carbon­yl)oxymethyl­carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol­ecule are related by a crystallographic mirror plane. Delocalization through the Zr—O—C=W unit is indicated by a short Zr—O distance and a nearly linear Zr—O—C angle.

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