Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)

The title compound, [ZrW(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)] or [W(CO)(5)C(CH(3))OZr(C(5)H(5))(2)Cl], consists of two metal centres, with a (tungsten penta­carbon­yl)oxymethyl­carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol­ecule are related by...

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Autores principales: Esterhuysen, Catharine, Neveling, Arno, Luruli, Nyambeni, Kruger, Gert J., Cronje, Stephanie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959354/
https://www.ncbi.nlm.nih.gov/pubmed/21201008
http://dx.doi.org/10.1107/S1600536808028006
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author Esterhuysen, Catharine
Neveling, Arno
Luruli, Nyambeni
Kruger, Gert J.
Cronje, Stephanie
author_facet Esterhuysen, Catharine
Neveling, Arno
Luruli, Nyambeni
Kruger, Gert J.
Cronje, Stephanie
author_sort Esterhuysen, Catharine
collection PubMed
description The title compound, [ZrW(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)] or [W(CO)(5)C(CH(3))OZr(C(5)H(5))(2)Cl], consists of two metal centres, with a (tungsten penta­carbon­yl)oxymethyl­carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol­ecule are related by a crystallographic mirror plane. Delocalization through the Zr—O—C=W unit is indicated by a short Zr—O distance and a nearly linear Zr—O—C angle.
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spelling pubmed-29593542010-12-30 Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV) Esterhuysen, Catharine Neveling, Arno Luruli, Nyambeni Kruger, Gert J. Cronje, Stephanie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ZrW(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)] or [W(CO)(5)C(CH(3))OZr(C(5)H(5))(2)Cl], consists of two metal centres, with a (tungsten penta­carbon­yl)oxymethyl­carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol­ecule are related by a crystallographic mirror plane. Delocalization through the Zr—O—C=W unit is indicated by a short Zr—O distance and a nearly linear Zr—O—C angle. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959354/ /pubmed/21201008 http://dx.doi.org/10.1107/S1600536808028006 Text en © Esterhuysen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Esterhuysen, Catharine
Neveling, Arno
Luruli, Nyambeni
Kruger, Gert J.
Cronje, Stephanie
Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)
title Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)
title_full Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)
title_fullStr Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)
title_full_unstemmed Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)
title_short Penta­carbonyl-2κ(5)C-chlorido-1κCl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) O:C]tungsten(0)zirconium(IV)
title_sort penta­carbonyl-2κ(5)c-chlorido-1κcl-bis­[1(η(5))-cyclo­penta­dien­yl][μ(2)-oxido(meth­yl)methyl­ene-1:2κ(2) o:c]tungsten(0)zirconium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959354/
https://www.ncbi.nlm.nih.gov/pubmed/21201008
http://dx.doi.org/10.1107/S1600536808028006
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