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3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone

The title bicyclic lactone, C(19)H(19)NO(3), is an inter­mediate in the synthesis of chiral α-methyl­prolines and branched C-methyl pyrrolidines; the absolute configuration was determined by the use of d-erythronolactone as the starting material. It exhibits no unusual crystal packing features, and...

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Detalles Bibliográficos
Autores principales: da Cruz, Filipa P., Booth, K. Victoria, Fleet, George W. J., Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959362/
https://www.ncbi.nlm.nih.gov/pubmed/21201113
http://dx.doi.org/10.1107/S1600536808027888
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author da Cruz, Filipa P.
Booth, K. Victoria
Fleet, George W. J.
Watkin, David J.
author_facet da Cruz, Filipa P.
Booth, K. Victoria
Fleet, George W. J.
Watkin, David J.
author_sort da Cruz, Filipa P.
collection PubMed
description The title bicyclic lactone, C(19)H(19)NO(3), is an inter­mediate in the synthesis of chiral α-methyl­prolines and branched C-methyl pyrrolidines; the absolute configuration was determined by the use of d-erythronolactone as the starting material. It exhibits no unusual crystal packing features, and each mol­ecule acts as a donor and acceptor for one C—H⋯O hydrogen bond.
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spelling pubmed-29593622010-12-30 3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone da Cruz, Filipa P. Booth, K. Victoria Fleet, George W. J. Watkin, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title bicyclic lactone, C(19)H(19)NO(3), is an inter­mediate in the synthesis of chiral α-methyl­prolines and branched C-methyl pyrrolidines; the absolute configuration was determined by the use of d-erythronolactone as the starting material. It exhibits no unusual crystal packing features, and each mol­ecule acts as a donor and acceptor for one C—H⋯O hydrogen bond. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959362/ /pubmed/21201113 http://dx.doi.org/10.1107/S1600536808027888 Text en © Cruz et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
da Cruz, Filipa P.
Booth, K. Victoria
Fleet, George W. J.
Watkin, David J.
3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone
title 3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone
title_full 3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone
title_fullStr 3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone
title_full_unstemmed 3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone
title_short 3-O-Benzhydryl-2,5-dide­oxy-2,5-imino-2-C-methyl-l-lyxono-1,4-lactone
title_sort 3-o-benzhydryl-2,5-dide­oxy-2,5-imino-2-c-methyl-l-lyxono-1,4-lactone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959362/
https://www.ncbi.nlm.nih.gov/pubmed/21201113
http://dx.doi.org/10.1107/S1600536808027888
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