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Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)

In the title compound, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(3))(2)], the Sb atom lies on an inversion centre and exhibits a trigonal bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions occupied by C atoms of the phenyl groups. Intra...

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Detalles Bibliográficos
Autores principales: Wen, Liyuan, Yin, Handong, Quan, Li, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959366/
https://www.ncbi.nlm.nih.gov/pubmed/21201042
http://dx.doi.org/10.1107/S1600536808029656
Descripción
Sumario:In the title compound, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(3))(2)], the Sb atom lies on an inversion centre and exhibits a trigonal bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions occupied by C atoms of the phenyl groups. Intra­molecular C—H⋯O hydrogen bonds stabilize the mol­ecular conformation. In the crystal structure, mol­ecules are connected by inter­molecular C—H⋯O hydrogen-bonding inter­actions, forming a layer structure parallel to ([Image: see text]01).