Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)

In the title compound, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(3))(2)], the Sb atom lies on an inversion centre and exhibits a trigonal bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions occupied by C atoms of the phenyl groups. Intra...

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Detalles Bibliográficos
Autores principales: Wen, Liyuan, Yin, Handong, Quan, Li, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959366/
https://www.ncbi.nlm.nih.gov/pubmed/21201042
http://dx.doi.org/10.1107/S1600536808029656
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author Wen, Liyuan
Yin, Handong
Quan, Li
Wang, Daqi
author_facet Wen, Liyuan
Yin, Handong
Quan, Li
Wang, Daqi
author_sort Wen, Liyuan
collection PubMed
description In the title compound, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(3))(2)], the Sb atom lies on an inversion centre and exhibits a trigonal bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions occupied by C atoms of the phenyl groups. Intra­molecular C—H⋯O hydrogen bonds stabilize the mol­ecular conformation. In the crystal structure, mol­ecules are connected by inter­molecular C—H⋯O hydrogen-bonding inter­actions, forming a layer structure parallel to ([Image: see text]01).
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spelling pubmed-29593662010-12-30 Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V) Wen, Liyuan Yin, Handong Quan, Li Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(3))(2)], the Sb atom lies on an inversion centre and exhibits a trigonal bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions occupied by C atoms of the phenyl groups. Intra­molecular C—H⋯O hydrogen bonds stabilize the mol­ecular conformation. In the crystal structure, mol­ecules are connected by inter­molecular C—H⋯O hydrogen-bonding inter­actions, forming a layer structure parallel to ([Image: see text]01). International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959366/ /pubmed/21201042 http://dx.doi.org/10.1107/S1600536808029656 Text en © Wen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Liyuan
Yin, Handong
Quan, Li
Wang, Daqi
Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)
title Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)
title_full Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)
title_fullStr Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)
title_full_unstemmed Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)
title_short Triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(V)
title_sort triphenyl­bis(2,4,5-trifluoro-3-methoxy­benzoato)anti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959366/
https://www.ncbi.nlm.nih.gov/pubmed/21201042
http://dx.doi.org/10.1107/S1600536808029656
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AT wangdaqi triphenylbis245trifluoro3methoxybenzoatoantimonyv

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