(Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate

In the title compound, [Mo(C(44)H(28)N(4))(NO(3))O]·C(6)H(6), the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and...

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Detalles Bibliográficos
Autores principales: Carter, Shawn M., Xu, Nan, Khan, Masood A., Powell, Douglas R., Richter-Addo, George B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959382/
https://www.ncbi.nlm.nih.gov/pubmed/21201070
http://dx.doi.org/10.1107/S1600536808030705
Descripción
Sumario:In the title compound, [Mo(C(44)H(28)N(4))(NO(3))O]·C(6)H(6), the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo—O bond to a nitrate O atom. A centrosymmetric benzene solvent mol­ecule is situated between adjacent porphyrin mol­ecules.

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