(Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate

In the title compound, [Mo(C(44)H(28)N(4))(NO(3))O]·C(6)H(6), the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and...

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Detalles Bibliográficos
Autores principales: Carter, Shawn M., Xu, Nan, Khan, Masood A., Powell, Douglas R., Richter-Addo, George B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959382/
https://www.ncbi.nlm.nih.gov/pubmed/21201070
http://dx.doi.org/10.1107/S1600536808030705
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author Carter, Shawn M.
Xu, Nan
Khan, Masood A.
Powell, Douglas R.
Richter-Addo, George B.
author_facet Carter, Shawn M.
Xu, Nan
Khan, Masood A.
Powell, Douglas R.
Richter-Addo, George B.
author_sort Carter, Shawn M.
collection PubMed
description In the title compound, [Mo(C(44)H(28)N(4))(NO(3))O]·C(6)H(6), the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo—O bond to a nitrate O atom. A centrosymmetric benzene solvent mol­ecule is situated between adjacent porphyrin mol­ecules.
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spelling pubmed-29593822010-12-30 (Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate Carter, Shawn M. Xu, Nan Khan, Masood A. Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(C(44)H(28)N(4))(NO(3))O]·C(6)H(6), the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo—O bond to a nitrate O atom. A centrosymmetric benzene solvent mol­ecule is situated between adjacent porphyrin mol­ecules. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959382/ /pubmed/21201070 http://dx.doi.org/10.1107/S1600536808030705 Text en © Carter et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Carter, Shawn M.
Xu, Nan
Khan, Masood A.
Powell, Douglas R.
Richter-Addo, George B.
(Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate
title (Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate
title_full (Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate
title_fullStr (Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate
title_full_unstemmed (Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate
title_short (Nitrato-κO)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)molybdenum(V) benzene solvate
title_sort (nitrato-κo)oxido(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)molybdenum(v) benzene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959382/
https://www.ncbi.nlm.nih.gov/pubmed/21201070
http://dx.doi.org/10.1107/S1600536808030705
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