Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)

In the title compound, [Mn(C(7)H(6)NO(4)S)(2)(H(2)O)(4)], the Mn atom, lying on an inversion center, exhibits a distorted octa­hedral coordination by six O atoms, two from carboxyl­ate groups and four from water mol­ecules. The SO(2)NH(2) group is involved in a three dimensional polymeric hydrogen b...

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Detalles Bibliográficos
Autores principales: Akram, Rehana, Siddiqui, Waseeq Ahmad, Tahir, M. Nawaz, Siddiqui, Hamid Latif, Iqbal, Amjid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959390/
https://www.ncbi.nlm.nih.gov/pubmed/21201036
http://dx.doi.org/10.1107/S1600536808029450
Descripción
Sumario:In the title compound, [Mn(C(7)H(6)NO(4)S)(2)(H(2)O)(4)], the Mn atom, lying on an inversion center, exhibits a distorted octa­hedral coordination by six O atoms, two from carboxyl­ate groups and four from water mol­ecules. The SO(2)NH(2) group is involved in a three dimensional polymeric hydrogen bonding network along with the water mol­ecules. π-Stacking inter­actions parallel to the c axis lead to a separation of 4.0050 (12) Å between the centroids of the benzene rings.

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