Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)

In the title compound, [Mn(C(7)H(6)NO(4)S)(2)(H(2)O)(4)], the Mn atom, lying on an inversion center, exhibits a distorted octa­hedral coordination by six O atoms, two from carboxyl­ate groups and four from water mol­ecules. The SO(2)NH(2) group is involved in a three dimensional polymeric hydrogen b...

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Autores principales: Akram, Rehana, Siddiqui, Waseeq Ahmad, Tahir, M. Nawaz, Siddiqui, Hamid Latif, Iqbal, Amjid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959390/
https://www.ncbi.nlm.nih.gov/pubmed/21201036
http://dx.doi.org/10.1107/S1600536808029450
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author Akram, Rehana
Siddiqui, Waseeq Ahmad
Tahir, M. Nawaz
Siddiqui, Hamid Latif
Iqbal, Amjid
author_facet Akram, Rehana
Siddiqui, Waseeq Ahmad
Tahir, M. Nawaz
Siddiqui, Hamid Latif
Iqbal, Amjid
author_sort Akram, Rehana
collection PubMed
description In the title compound, [Mn(C(7)H(6)NO(4)S)(2)(H(2)O)(4)], the Mn atom, lying on an inversion center, exhibits a distorted octa­hedral coordination by six O atoms, two from carboxyl­ate groups and four from water mol­ecules. The SO(2)NH(2) group is involved in a three dimensional polymeric hydrogen bonding network along with the water mol­ecules. π-Stacking inter­actions parallel to the c axis lead to a separation of 4.0050 (12) Å between the centroids of the benzene rings.
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spelling pubmed-29593902010-12-30 Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II) Akram, Rehana Siddiqui, Waseeq Ahmad Tahir, M. Nawaz Siddiqui, Hamid Latif Iqbal, Amjid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(7)H(6)NO(4)S)(2)(H(2)O)(4)], the Mn atom, lying on an inversion center, exhibits a distorted octa­hedral coordination by six O atoms, two from carboxyl­ate groups and four from water mol­ecules. The SO(2)NH(2) group is involved in a three dimensional polymeric hydrogen bonding network along with the water mol­ecules. π-Stacking inter­actions parallel to the c axis lead to a separation of 4.0050 (12) Å between the centroids of the benzene rings. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959390/ /pubmed/21201036 http://dx.doi.org/10.1107/S1600536808029450 Text en © Akram et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akram, Rehana
Siddiqui, Waseeq Ahmad
Tahir, M. Nawaz
Siddiqui, Hamid Latif
Iqbal, Amjid
Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)
title Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)
title_full Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)
title_fullStr Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)
title_full_unstemmed Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)
title_short Tetra­aquabis­(2-sulfamoylbenzoato)manganese(II)
title_sort tetra­aquabis­(2-sulfamoylbenzoato)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959390/
https://www.ncbi.nlm.nih.gov/pubmed/21201036
http://dx.doi.org/10.1107/S1600536808029450
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AT tahirmnawaz tetraaquabis2sulfamoylbenzoatomanganeseii
AT siddiquihamidlatif tetraaquabis2sulfamoylbenzoatomanganeseii
AT iqbalamjid tetraaquabis2sulfamoylbenzoatomanganeseii

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