trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II)

The title compound, [Cu(ClO(4))(2)(C(3)H(4)N(2))(4)], was obtained unexpectedly by the reaction of copper(II) perchlorate hexa­hydrate with equimolar amounts of 1-chloro-1-nitro-2,2,2-tripyrazolylethane in methanol solution. The crystal structure comprises octa­hedrally coordinated Cu(2+) ions, loca...

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Autores principales: Edelmann, Frank T., Kaufmann, Dieter E., Blaurock, Steffen, Wagner, Thomas, Zapol’skii, Viktor
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959392/
https://www.ncbi.nlm.nih.gov/pubmed/21201051
http://dx.doi.org/10.1107/S1600536808030080
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author Edelmann, Frank T.
Kaufmann, Dieter E.
Blaurock, Steffen
Wagner, Thomas
Zapol’skii, Viktor
author_facet Edelmann, Frank T.
Kaufmann, Dieter E.
Blaurock, Steffen
Wagner, Thomas
Zapol’skii, Viktor
author_sort Edelmann, Frank T.
collection PubMed
description The title compound, [Cu(ClO(4))(2)(C(3)H(4)N(2))(4)], was obtained unexpectedly by the reaction of copper(II) perchlorate hexa­hydrate with equimolar amounts of 1-chloro-1-nitro-2,2,2-tripyrazolylethane in methanol solution. The crystal structure comprises octa­hedrally coordinated Cu(2+) ions, located on an inversion centre, with four pyrazole ligands in the equatorial plane. The average Cu—N distance is 2.000 (1) Å. Two perchlorate ions are coordinated to copper in trans positions [Cu—O = 2.4163 (11) Å].
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spelling pubmed-29593922010-12-30 trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II) Edelmann, Frank T. Kaufmann, Dieter E. Blaurock, Steffen Wagner, Thomas Zapol’skii, Viktor Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(ClO(4))(2)(C(3)H(4)N(2))(4)], was obtained unexpectedly by the reaction of copper(II) perchlorate hexa­hydrate with equimolar amounts of 1-chloro-1-nitro-2,2,2-tripyrazolylethane in methanol solution. The crystal structure comprises octa­hedrally coordinated Cu(2+) ions, located on an inversion centre, with four pyrazole ligands in the equatorial plane. The average Cu—N distance is 2.000 (1) Å. Two perchlorate ions are coordinated to copper in trans positions [Cu—O = 2.4163 (11) Å]. International Union of Crystallography 2008-09-24 /pmc/articles/PMC2959392/ /pubmed/21201051 http://dx.doi.org/10.1107/S1600536808030080 Text en © Edelmann et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Edelmann, Frank T.
Kaufmann, Dieter E.
Blaurock, Steffen
Wagner, Thomas
Zapol’skii, Viktor
trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II)
title trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II)
title_full trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II)
title_fullStr trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II)
title_full_unstemmed trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II)
title_short trans-Bis(perchlorato-κO)tetra­kis(1H-pyrazole-κN (2))copper(II)
title_sort trans-bis(perchlorato-κo)tetra­kis(1h-pyrazole-κn (2))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959392/
https://www.ncbi.nlm.nih.gov/pubmed/21201051
http://dx.doi.org/10.1107/S1600536808030080
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AT blaurocksteffen transbisperchloratokotetrakis1hpyrazolekn2copperii
AT wagnerthomas transbisperchloratokotetrakis1hpyrazolekn2copperii
AT zapolskiiviktor transbisperchloratokotetrakis1hpyrazolekn2copperii

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