Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]

In the title complex, [Ce(2)(C(8)H(5)NO(4))(3)(H(2)O)(2)](n), each Ce ion is in nine-coordinated environment. Eight O atoms from six ligands participate in coordination, in addition to one O atom from a water mol­ecule. Both carboxyl­ate groups from the ligands chelate the Ce atoms, forming two four...

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Detalles Bibliográficos
Autores principales: Ma, Hui-Jie, Fan, Yu-Hua, Wang, Qiang, Bi, Cai-Feng, Zhang, Dong-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959393/
https://www.ncbi.nlm.nih.gov/pubmed/21201061
http://dx.doi.org/10.1107/S160053680803033X
Descripción
Sumario:In the title complex, [Ce(2)(C(8)H(5)NO(4))(3)(H(2)O)(2)](n), each Ce ion is in nine-coordinated environment. Eight O atoms from six ligands participate in coordination, in addition to one O atom from a water mol­ecule. Both carboxyl­ate groups from the ligands chelate the Ce atoms, forming two four-membered rings. The 5-amino­isophthalate ligands also bridge the Ce centers, forming a two-dimensional network, and O—H⋯O and N—H⋯O hydrogen bonds complete the structure.

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