Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]

In the title complex, [Ce(2)(C(8)H(5)NO(4))(3)(H(2)O)(2)](n), each Ce ion is in nine-coordinated environment. Eight O atoms from six ligands participate in coordination, in addition to one O atom from a water mol­ecule. Both carboxyl­ate groups from the ligands chelate the Ce atoms, forming two four...

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Autores principales: Ma, Hui-Jie, Fan, Yu-Hua, Wang, Qiang, Bi, Cai-Feng, Zhang, Dong-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959393/
https://www.ncbi.nlm.nih.gov/pubmed/21201061
http://dx.doi.org/10.1107/S160053680803033X
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author Ma, Hui-Jie
Fan, Yu-Hua
Wang, Qiang
Bi, Cai-Feng
Zhang, Dong-Mei
author_facet Ma, Hui-Jie
Fan, Yu-Hua
Wang, Qiang
Bi, Cai-Feng
Zhang, Dong-Mei
author_sort Ma, Hui-Jie
collection PubMed
description In the title complex, [Ce(2)(C(8)H(5)NO(4))(3)(H(2)O)(2)](n), each Ce ion is in nine-coordinated environment. Eight O atoms from six ligands participate in coordination, in addition to one O atom from a water mol­ecule. Both carboxyl­ate groups from the ligands chelate the Ce atoms, forming two four-membered rings. The 5-amino­isophthalate ligands also bridge the Ce centers, forming a two-dimensional network, and O—H⋯O and N—H⋯O hydrogen bonds complete the structure.
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spelling pubmed-29593932010-12-30 Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)] Ma, Hui-Jie Fan, Yu-Hua Wang, Qiang Bi, Cai-Feng Zhang, Dong-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ce(2)(C(8)H(5)NO(4))(3)(H(2)O)(2)](n), each Ce ion is in nine-coordinated environment. Eight O atoms from six ligands participate in coordination, in addition to one O atom from a water mol­ecule. Both carboxyl­ate groups from the ligands chelate the Ce atoms, forming two four-membered rings. The 5-amino­isophthalate ligands also bridge the Ce centers, forming a two-dimensional network, and O—H⋯O and N—H⋯O hydrogen bonds complete the structure. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959393/ /pubmed/21201061 http://dx.doi.org/10.1107/S160053680803033X Text en © Ma et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Hui-Jie
Fan, Yu-Hua
Wang, Qiang
Bi, Cai-Feng
Zhang, Dong-Mei
Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]
title Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]
title_full Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]
title_fullStr Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]
title_full_unstemmed Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]
title_short Poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(III)]
title_sort poly[tris­(μ(3)-5-amino­isophthalato)diaqua­dicerium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959393/
https://www.ncbi.nlm.nih.gov/pubmed/21201061
http://dx.doi.org/10.1107/S160053680803033X
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